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In this research, the structural characteristics, specific surface area, sorption of water vapor, and wetting enthalpy of various polysaccharides (cellulose, hemicelluloses, starch, pectin, chitin, and chitosan) have been studied. It was confirmed that crystallites are inaccessible for water, and therefore water molecules can interact only with polar groups in noncrystalline (amorphous) domains of biopolymers. The...