Studies on Calcium Sulfoaluminate-Belite (CSAB) Cement Using Industrial Wastes

Authors

  • Amit Yadav

    CSIR-Central Building Research Institute, Roorkee 247667, India

  • Rajesh Kumar

    CSIR-Central Building Research Institute, Roorkee 247667, India

    Academy of Scientific and Innovative Research (AcSIR), Ghaziabad 201002, India

  • Charu Mehta

    CSIR-Central Building Research Institute, Roorkee 247667, India

  • Nikhil Sanjay Nighot

    CSIR-Central Building Research Institute, Roorkee 247667, India

    Academy of Scientific and Innovative Research (AcSIR), Ghaziabad 201002, India

  • Srinivasarao Naik B.

    CSIR-Central Building Research Institute, Roorkee 247667, India

    Academy of Scientific and Innovative Research (AcSIR), Ghaziabad 201002, India

DOI:

https://doi.org/10.30564/jbms.v8i1.9136
Received: 18 March 2025 | Revised: 3 April 2025 | Accepted: 11 April 2025 | Published Online: 5 January 2026

Abstract

Researchers and engineers have been looking at novel approaches to develop cementitious materials with decreased environmental impact without sacrificing performance and durability in response to these difficulties. Calcium Sulfoaluminate-Belite cement (CSAB) is a value-added binder that has gained popularity for its unique qualities and benefits. The CSAB cement system is regarded as an innovative and promising sustainable construction material that helps to mitigate the environmental consequences of regular Portland cement. CSAB cement has been developed as a more sustainable alternative to Portland cement because of its lower energy consumption and CO2 emissions. The presented study examines the modern research to develop newly produced cement known as CSAB cement. Also, ongoing research activities at the author institute to synthesize CSAB binders using different kinds of low-graded industrial waste materials such as low-grade limestone and phosphogypsum has been presented, which makes it innovative. Physico-mechanical parameters such as setting time and compressive strength were compared in various investigations. CSAB cement quick setting periods and early strength development allow for a greater amount of work to be accomplished within the project timeline. In the various investigations the compressive strength data revealed impressive results ranging from 39.0 to 45.10 MPa, demonstrating the material robust structural capabilities. The mineralogical composition of CSAB cement primarily consists of ye'elimite (C4A3S), belite (C2S), ferrite (C4AF), and anhydrite (CS), contributes to both the rapid setting characteristics and the development of substantial compressive strength. It has been observed that CSAB cement manufacturing can provide up to 30% reduction in carbon footprint as its manufacturing process requires lower kiln temperatures which results in lower energy consumption and associated emissions from fuel combustion.

Keywords:

Low Carbon Cement; Compressive Strength; Setting Time; CSAB Cement; Sustainability

References

[1] Huang, X., Luo, X., Liu, Y., et al., 2024. Research on the properties of low carbon composite cement. Materials Letters. 361, 136044. DOI: https://doi.org/10.1016/j.matlet.2024.136044

[2] Chaunsali, P., Vaishnav, K., 2020. Calcium-sulfoaluminate-belite cement: Opportunities and challenges. Indian Concrete Journal. 94, 18–25.

[3] Tao, Y., Rahul, A.V., Mohan, M.K., et al., 2023. Recent progress and technical challenges in using calcium sulfoaluminate (CSA) cement. Cement and Concrete Composites. 137, 104908. DOI: https://doi.org/10.1016/j.cemconcomp.2022.104908

[4] Tambara, L.U.D., Cheriaf, M., Rocha, J.C., et al., 2020. Effect of alkalis content on calcium sulfoaluminate (CSA) cement hydration. Cement and Concrete Research. 128, 105953. DOI: https://doi.org/10.1016/j.cemconres.2019.105953

[5] Marroccoli, M., Telesca, A., Lothenbach, B., et al., 2025. Synthesis and properties of a belite–calcium sulfoaluminate cement obtained using only waste materials. Advances in Cement Research. 37(2), 78–88. DOI: https://doi.org/10.1680/jadcr.24.00005

[6] Aliti, R., 2019. Hydration processes in calcium sulfoaluminate (CSA) and calcium sulfoaluminate-belite (CSAB) binders. Journal of Natural Sciences and Mathematics of UT. 4(7–8), 259–268.

[7] Piekkari, K., Isteri, V., Ohenoja, K., et al., 2021. Effect of Gypsum Content on CSAB Cement-Based Immobilization of Se and SO4 from Industrial Filter Sludge and Sodium-Selenium Salts. Journal of Hazardous, Toxic, and Radioactive Waste. 25(3), 04021018. DOI: https://doi.org/10.1061/(ASCE)HZ.2153-5515.0000623

[8] Jia, F., Sun, H., Yu, L., et al., 2023. Effects of Different Gypsum Varieties on the Hydration and Mechanical Properties of Red Mud-Based Ferrite-Rich Sulfoaluminate Cement. Journal of Materials Research and Technology. 24, 3086–3097. DOI: https://doi.org/10.1016/j.jmrt.2023.03.197

[9] Shenbagam, V.K., Shaji, P., Eswita, Y., et al., 2024. Carbonation of Calcium Sulfoaluminate Belite Binder: Mechanism and Its Implication on Properties. Journal of Sustainable Cement-Based Materials. 13(6), 938–950. DOI: https://doi.org/10.1080/21650373.2024.2306271

[10] Wong, L.S., 2022. Durability Performance of Geopolymer Concrete: A Review. Polymers. 14(5), 868. DOI: https://doi.org/10.3390/polym14050868

[11] Dhandapani, Y., Sakthivel, T., Santhanam, M., et al., 2018. Mechanical Properties and Durability Performance of Concretes with Limestone Calcined Clay Cement (LC3). Cement and Concrete Research. 107, 136–151. DOI: https://doi.org/10.1016/j.cemconres.2018.02.005

[12] Ma, J., Yu, Z., Ni, C., et al., 2019. Effects of Limestone Powder on the Hydration and Microstructure Development of Calcium Sulphoaluminate Cement Under Long-Term Curing. Construction and Building Materials. 199, 688–695. DOI: https://doi.org/10.1016/j.conbuildmat.2018.12.054

[13] Ke, G., Zhang, J., Liu, Y., et al., 2021. Pore Characteristics of Calcium Sulfoaluminate Cement Paste with Impact of Supplementary Cementitious Materials and Water to Binder Ratio. Powder Technology. 387, 146–155. DOI: https://doi.org/10.1016/j.powtec.2021.04.027

[14] Chen, I.A., Juenger, M.C.G., 2012. Incorporation of Coal Combustion Residuals into Calcium Sulfoaluminate-Belite Cement Clinkers. Cement and Concrete Composites. 34(8), 893–902. DOI: https://doi.org/10.1016/j.cemconcomp.2012.04.006

[15] Isteri, V., Ohenoja, K., Hanein, T., et al., 2020. Production and Properties of Ferrite-Rich CSAB Cement from Metallurgical Industry Residues. Science of The Total Environment. 712, 136208. DOI: https://doi.org/10.1016/j.scitotenv.2019.136208

[16] Jeong, Y., Hargis, C., Chun, S., et al., 2017. Effect of Calcium Carbonate Fineness on Calcium Sulfoaluminate-Belite Cement. Materials. 10(8), 900. DOI: https://doi.org/10.3390/ma10080900

[17] Jewell, R., Rathbone, R., Duvallet, T., et al., 2015. Fabrication and Testing of Low-Energy Calcium Sulfoaluminate-Belite Cements that Utilize Circulating Fluidized Bed Combustion By-Products. DOI: https://doi.org/10.4177/CCGP-D-15-00001.1

[18] Shen, Y., Qian, J., Huang, Y., et al., 2015. Synthesis of Belite Sulfoaluminate-Ternesite Cements with Phosphogypsum. Cement and Concrete Composites. 63, 67–75. DOI: https://doi.org/10.1016/j.cemconcomp.2015.09.003

[19] Ma, B., Li, X., Mao, Y., et al., 2013. Synthesis and Characterization of High Belite Sulfoaluminate Cement through Rich Alumina Fly Ash and Desulfurization Gypsum. Ceramics-Silikáty, 57(1), 7–13.

[20] Rungchet, A., Poon, C.S., Chindaprasirt, P., et al., 2017. Synthesis of Low-Temperature Calcium Sulfoaluminate-Belite Cements from Industrial Wastes and Their Hydration: Comparative Studies Between Lignite Fly Ash and Bottom Ash. Cement and Concrete Composites. 83, 10–19. DOI: https://doi.org/10.1016/j.cemconcomp.2017.06.013

[21] Shen, Y., Chen, X., Zhang, W., et al., 2019. Effect of Ternesite on the Hydration and Properties of Calcium Sulfoaluminate Cement. Journal of Thermal Analysis and Calorimetry. 136(2), 687–695. DOI: https://doi.org/10.1007/s10973-018-7685-x

[22] Qin, L., Gao, X., Zhang, A., 2018. Potential Application of Portland Cement-Calcium Sulfoaluminate Cement Blends to Avoid Early Age Frost Damage. Construction and Building Materials. 190, 363–372. DOI: https://doi.org/10.1016/j.conbuildmat.2018.09.136

[23] Wang, Y., Yu, J., Wang, J., et al., 2019. Effects of Aluminum Sulfate and Quicklime/Fluorgypsum Ratio on the Properties of Calcium Sulfoaluminate (CSA) Cement-Based Double Liquid Grouting Materials. Materials. 12(8), 1222. DOI: https://doi.org/10.3390/ma12081222

[24] Burris, L.E., Kurtis, K.E., 2022. Water-to-Cement Ratio of Calcium Sulfoaluminate Belite Cements: Hydration, Setting Time, and Strength Development. Cement. 8, 100032. DOI: https://doi.org/10.1016/j.cement.2022.100032

[25] Nighot, N.S., Kumar, R., Naik, B.S., 2024. Effects of Bogues Compounds and Particle Size Distribution on the Physico-mechanical and Microstructural Properties of Portland Cement System. E3S Web of Conferences. 596, 01004. DOI: https://doi.org/10.1051/e3sconf/202459601004

[26] Nighot, N.S., Kumar, R., 2023. A Comprehensive Study on the Synthesis and Characterization of Eco-Cementitious Binders Using Different Kind of Industrial Wastes for Sustainable Development. Developments in the Built Environment. 14, 100135. DOI: https://doi.org/10.1016/j.dibe.2023.100135

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How to Cite

Yadav, A., Kumar, R., Mehta, C., Nighot, N. S., & B., S. N. (2026). Studies on Calcium Sulfoaluminate-Belite (CSAB) Cement Using Industrial Wastes. Journal of Building Material Science, 8(1), 1–11. https://doi.org/10.30564/jbms.v8i1.9136