Utilizing Nano-TiO2 and GGBS to Improve Concrete’s Acid Resistance and Durability

Authors

  • Mamidi Srinivasan

    Department of Civil Engineering, College of Engineering, Science & Technology, Jawaharlal Nehru Technological University, Hyderabad 500085, India

  • P. Sravana

    Department of Civil Engineering, College of Engineering, Science & Technology, Jawaharlal Nehru Technological University, Hyderabad 500085, India

DOI:

https://doi.org/10.30564/jbms.v7i2.9696
Received: 25 April 2025 | Revised: 23 May 2025 | Accepted: 26 May 2025 | Published Online: 12 June 2025

Abstract

Although concrete is a commonly used building material, it suffers deterioration in acidic surroundings. Significant structural damage and expensive repairs can follow from this. This work examined the strength and durability of M40 and M50 grade concrete incorporating 30% ground granulated blast furnace slag (GGBS) and 1% titanium dioxide (TiO₂). Several tests, including an acid resistance and fast chloride penetration test (RCPT), evaluated this altered concrete's performance. Over 28, 90, and 180 days, the acid resistance test assessed the effects of 5% sulphuric acid (H₂SO₄), hydrochloric acid (HCl), and sodium sulfate (Na₂SO₄). The modified concrete showed less weight loss and more residual compressive strength than conventional concrete, according the findings. The calculations of the acid durability factor verified that the modified concrete mix showed better resistance against hostile chemical surroundings. Measuring the overall charge passed through concrete specimens, the Rapid Chloride Penetration Test (RCPT) evaluated chloride ion permeability. Classifying the modified concrete as “very low”, it displayed a notable decrease in chloride penetration with roughly (50–60)% lower permeability for M40 and (40–50)% for M50 compared to the control mix.

Keywords:

Concrete Pavement; Nano Titanium Dioxide (TiO₂); Ground Granulated Blast Furnace Slag (GGBS); Acid Attack Resistance; RCPT; Durability

References

[1] Adebanjo, A.U., Abbas, Y.M., Shafiq, N., et al., 2024. Optimizing nano-TiO2 and ZnO integration in silica-based high-performance concrete: Mechanical, durability, and photocatalysis insights for sustainable self-cleaning systems. Construction and Building Materials. 446, 138038. DOI: https://doi.org/10.1016/j.conbuildmat.2024.138038

[2] Baikerikar, A.V., Ganachari, V., Khed, V.C., et al., 2024. Synergistic effects of nano titanium dioxide and waste glass powder on the mechanical and durability properties of concrete. Scientific Reports. 14(1), 27573. DOI: https://doi.org/10.1038/s41598-024-79263-9

[3] Dhanapal, J., Saravanan, S., Jayaprakash, S., et al., 2024. Eco-Friendly Concrete Solutions: The Role of Titanium Dioxide Nanoparticles in Enhancing Durability and Reducing Environmental Pollutants-A Review. Journal of Environmental Nanotechnology. 13(3), 332–344. DOI: https://doi.org/10.13074/jent.2024.09.243894

[4] Döndüren, M.S., Al-Hagri, M.G., 2022. A review of the effect and optimization of use of nano-TiO2 in cementitious composites. Research on Engineering Structures and Materials. 8(2), 283–305. DOI: http://dx.doi.org/10.17515/resm2022.348st1005

[5] Maniseresht, A., 2024. Exploring the Impact of TiO2 and Ggbs on Rcc Pavements Via Rsm. Available from: https://papers.ssrn.com/sol3/papers.cfm?abstract_id=4855621 (cited 15 April 2025).

[6] Maraş, M.M., 2021. Mechanical and fracture behavior of geopolymer composites reinforced with fibers by using nano-TiO2. Journal of the Brazilian Society of Mechanical Sciences and Engineering. 43(9), 412. DOI: https://doi.org/10.1007/s40430-021-03135-w

[7] Mustafa Mohamed, A., Tayeh, B.A., Ahmed, T.I., et al., 2025. Influence of nano-silica and nano-ferrite particles on mechanical and durability of sustainable concrete: A review. Nanotechnology Reviews. 14(1), 20250151. DOI: https://doi.org/10.1515/ntrev-2025-0151

[8] Pathak, S.S., Vesmawala, G.R., 2023. Influence of Nano-TiO2 and water to cement ratio on fracture parameters of concrete. Asian Journal of Civil Engineering. 24(7), 1969–1979. DOI: https://doi.org/10.1007/s42107-023-00616-2

[9] Pathak, S., Vesmawala, G., 2025. Evaluation of fracture parameters of concrete notched beams containing Nano TiO2 and ground granulated blast furnace slag. Journal of Building Pathology and Rehabilitation. 10(1), 49. DOI: https://doi.org/10.1007/s41024-024-00560-x

[10] Rao, M.S.C., Packialakshmi, S., Rath, B., et al., 2023. Utilization of agricultural, industrial waste and nanosilica as replacement for cementitious material and natural aggregates–Mechanical, microstructural and durability characteristics assessment. Environmental Research. 231, 116010. DOI: https://doi.org/10.1016/j.envres.2023.116010

[11] Raza, A., Azab, M., Baki, Z.A., et al., 2023. Experimental study on mechanical, toughness and microstructural characteristics of micro-carbon fibre-reinforced geopolymer having nano TiO2. Alexandria Engineering Journal. 64, 451–463. DOI: https://doi.org/10.1016/j.aej.2022.09.001

[12] Salama, A.H.E.-S., Assolie, A.A., Alsafasfeh, A., 2024. Mechanical Performance and Microstructure Evolution of Nano-Titanium dioxide Enhanced Cement–A Comprehensive Experimental Analysis. Advances in Science and Technology. Research Journal. 18(7). DOI: https://doi.org/10.12913/22998624/193524

[13] Sharma, J., Chaturvedi, G.K., Pandey, U.K., 2024. Impact of Nano Titanium Dioxide on Rubberized Concrete: Evaluating Physical, Mechanical, and Durability Characteristics. Mechanical, and Durability Characteristics. Available from: https://papers.ssrn.com/sol3/papers.cfm?abstract_id=5072487 (cited 15 April 2025).

[14] Shumuye, E.D., Liu, C., Fang, G., et al., 2024. Utilization of photocatalytic degradation and efficiency of engineered geopolymer composite tile doped with nano-particles under ultraviolet light. Cement and Concrete Composites. 153, 105729. DOI: https://doi.org/10.1016/j.cemconcomp.2024.105729

[15] Sivasakthi, M., Jeyalakshmi, R., Rajamane, N.P., 2021. Investigation of Microstructure and Thermomechanical Properties of Nano-TiO2 Admixed Geopolymer for Thermal Resistance Applications. Journal of Materials Engineering and Performance. 30(5), 3642–3653. DOI: https://doi.org/10.1007/s11665-021-05708-1

[16] Srivastava, A., Mishra, A., Singh, S.K., 2025. An effect of nano alumina and nano titanium di oxide with polypropylene fiber on the concrete: Mechanical and durability study. Discover Civil Engineering. 2(1), 6. DOI: https://doi.org/10.1007/s44290-025-00161-8

[17] Srivastava, A., Mishra, A., Singh, S.K., 2025b. Mechanical and durability study of nano-SiO2 and nano-TiO2 on fiber reinforced concrete. Challenge. 16(1), 33–39. DOI: https://doi.org/10.20528/cjcrl.2025.01.004

[18] Tanimola, J.O., Efe, S., 2024. Recent Advances in Nano-Modified Concrete: Enhancing Durability, Strength, and Sustainability Through Nano Silica (nS) and Nano Titanium (nT) Incorporation. Applications in Engineering Science. 19, 100189. DOI: https://doi.org/10.1016/j.apples.2024.100189

[19] Tanyildizi, H., Yilmaz, A., Açik, V., et al., 2024. Self-Cleaning Performance of Basalt Fiber–Reinforced GGBS-Based Geopolymer Mortar Containing Nano TiO2. Journal of Materials in Civil Engineering. 36(8), 04024205. DOI: https://doi.org/10.1061/JMCEE7.MTENG-17155

[20] Vaid, U., Lallotra, B., 2024. Effect on concrete strength and durability with partial replacement of cement by Nano-titanium dioxide (nano-TiO2) and ground granulated blast furnace slag (GGBS): A Review Summary. IOP Conference Series: Earth and Environmental Science. 1326(1), 012046. DOI: https://doi.org/10.1088/1755-1315/1326/1/012046

[21] Yu, X., Xu, X., Yang, X., et al., 2023. High fire stability cement composite cementitious material based on semi‐dry gas desulfurized ash/blast furnace slag system: The synergistic effect of nano‐TiO2 and nano‐SiO2. Asia-Pacific Journal of Chemical Engineering. 18(3), e2883. DOI: https://doi.org/10.1002/apj.2883

[22] Zhang, S.-L., Qi, X.-Q., Guo, S.-Y., et al., 2021. Effect of a novel hybrid TiO2-graphene composite on enhancing mechanical and durability characteristics of alkali-activated slag mortar. Construction and Building Materials. 275, 122154. DOI: https://doi.org/10.1016/j.conbuildmat.2020.122154

[23] Ziada, M., 2024. The Effect of Nano-TiO2 and Nano-Al2O3 on Mechanical, Microstructure Properties and High-Temperature Resistance of Geopolymer Mortars. Arabian Journal for Science and Engineering. DOI: https://doi.org/10.1007/s13369-024-09570-w

[24] Harle, S.M., 2014. Review on the performance of glass fiber reinforced concrete. International Journal of Civil Engineering Research. 5(3), 281–284.

[25] Chitkeshwar, A.K., Naktode, P.L., 2022. Concrete with rock quarry dust with partial replacement of fine aggregate. Materials Today: Proceedings. 62, 6455–6459. DOI: https://doi.org/10.1016/j.matpr.2022.04.195

[26] Wankhade, R.L., Landage, A.B., 2013. Non-destructive testing of concrete structures in Karad region. Procedia Engineering. 51, 8–18.

[27] Nadi, S., Beheshti Nezhad, H., Sadeghi, A., 2022. Experimental study on the durability and mechanical properties of concrete with crumb rubber. Journal of Building Pathology and Rehabilitation. 7, 1–12.

[28] Karthikeyan, B., Dhinakaran, G., 2018. Influence of ultrafine TiO2 and silica fume on performance of unreinforced and fiber reinforced concrete. Construction and Building Materials. 161, 570–576.

[29] Nejati, M.Y., Behruyan, M., Sadeghi, A., et al., 2025. Experimental Study on the Compressive and Flexural Properties of the Ultrahigh-Performance Concrete Containing Fibers. Journal of Building Material Science. 7(1), 83–96. DOI: https://doi.org/10.30564/jbms.v7i1.8269

[30] Torres, A., Ellis, F.A.S.A.M., 2020. The Effect of Various Polynaphthalene Sulfonate Based Superplasti-cizers on the Workability of Reactive Powder Concrete. Journal of Building Material Science. 2(1), 2–29. DOI: https://doi.org/10.30564/jbms.v2i1.2731

[31] Islam, N., A Gafur, M., 2023. Matrix-Material Fabrication Technique and Thermogravimetric Analysis of Banana Fiber Reinforced Polypropylene Composites. Journal of Building Material Science. 5(2), 15–24. DOI: https://doi.org/10.30564/jbms.v5i2.5700

[32] Snoeck, D., Steuperaert, S., Van Tittelboom, K., et al., 2012. Visualization of water penetration in cementitious materials with superabsorbent polymers by means of neutron radiography. Cement and Concrete Research. 42(8), 1113–1121.

[33] Jefferson, A., Joseph, C., Lark, R., et al., 2010. A new system for crack closure of cementitious materials using shrinkable polymers. Cement and Concrete Research. 40(5), 795–801.

[34] Galano, S., Calabrese, A., Asvapathanagul, P., et al., 2025. Innovative Approaches to Enhancing Concrete Compressive Strength: An Extensive Investigation of Biochar-Embedded and Self-Repairing Techniques. Journal of Materials in Civil Engineering. 37(5), 04025112.

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How to Cite

Srinivasan, M., & P. Sravana. (2025). Utilizing Nano-TiO2 and GGBS to Improve Concrete’s Acid Resistance and Durability. Journal of Building Material Science, 7(2), 175–192. https://doi.org/10.30564/jbms.v7i2.9696