V. I. Kodolov
Basic Research - High Educational Centre of Chemical Physics and Mesoscopics, Udmurt Federal Research Centre,UD, RAS, Izhevsk, Russia;M.T. Kalashnikov Izhevsk State Technical University, Izhevsk, Russia
V.V. Kodolova Chukhontseva
Institute Macromolecular Compounds, RAS, StPetersburg, Russia
The estimation of chemical particles reactivity and the determination of chemical reactions direction are the actual theme in new scientific trend - Chemical Mesoscopics. Paper includes the proposal about the using the theory of free energy linear dependence from physical organic chemistry and their applications for prognosis of reactions flowing. The semi-empiric constants is given according to mesoscopic physics definitions as well as the transformed Kolmogorov-Avrami equation is discussed. It is the development of Chemical Mesoscopics for organic reactivity estimation including nanostructures reactivity
[1] V.I. Kodolov, V.V. Kodolova-Chukhotzeva. Fundamentals of Chemical Physics. Izhevsk: M.T. Kalashnikov IzhSTU, 2019: 218.
[2] V.A. Pal’m. The introduction in theoretical organic chemistry. M.: Publ. “High School”, 1974: 446.
[3] V.I. Kodolov. Possibilities of modeling in organic chemistry. Organic Reactivity, 1965, 2(4-6): 11-17.
[4] V.I. Kodolov, S.S. Spasskiy. Parameters in Alfrey-Price and Taft equations. Vysokomol. Soed., 1976, 18(9): 1986-1992.
