-
1507
-
1080
-
1076
-
625
-
590
PVA Based Polymer Electrolyte with Layered Filler Graphite for Natural Dye Sensitized Solar Cell
DOI:
https://doi.org/10.30564/nmms.v3i1.3301Abstract
Graphite nanopowder is synthesized by mechanical method using ball mill and used as filler in polymer electrolyte film based on Polyvinyl alcohol (PVA) for application in natural dye sensitized solar cell (DSSC). In the present work dye sensitized solar cell has been assembled using electrolyte system composed of PVA as host polymer, ethylene carbonate as plasticizer, LiI: I2 as redox couple and graphite as filler; TiO2 modified with Copper oxide (CuO) photoanode in order to provide inherent energy barrier and natural cocktail dye as sensitizer. The obtained solar cell conversion efficiency was about 3.2 % with fill factor 52% using an irradiation of 100 mW/cm2 at 25º C.
Keywords:
Polyvinyl alcohol; DSSC; Graphite; Copper oxide; Cocktail dyeReferences
[1] M. Gratzel. 2005. Solar energy conversion by dye sensitized photovoltaic cells. Inorganic Chemistry, 44, 6841-6851.
[2] M.H. Khanmirazaei, S. Ramesh and K. Ramesh. 2015. Polymer electrolyte based dye sensitized solar cell with rice starch and I methyl-3- propylimidazolium iodide ionic liquid. Material and Design, 85, 833- 837.
[3] H. Jauhari. R. Grover, N. Gupta, O. Nanda, D.S. Mehta and K. Saxena. 2018. Solid state dye sensitized solar cell with polyaniline thiourea based polymer electrolyte composition. Journal of renewable and sustainable energy, 10, 033502.
[4] K. Qiu and A.N. Netravali. 2012. Fabrication and characterization of biodegradable composites based on microfibrillated cellulose and polyvinyl alcohol. Compos. Sci. Technol., 2012, 1588-1594.
[5] S. Rajkumar, M.N. Kumar, K. Suguna, S. Muthulakshmi and R.A. Kumar. 2019. Enhanced performance of dye sensitized solar cell using natural cocktail dye as sensitizer. Optik, 178, 224-230.
[6] N. Mariotti, M. Bonamo, L. Fagiolari, N. Barbero, C. Gerbaldi, F. Bella and C. Barolo. 2020. Recent advances in eco-friendly and cost-effective materials towards sustainable dye sensitized solar cell. Green chemistry, 22, 7168-7218.
[7] R. Upadhyay, M. Tripathi, P. Chawla and A. Pandey. 2014. Performance of CeO2- TiO2 admixed photoelectrode for natural dye sensitized solar cell. J. Solid State Electrochem. 18,1889-1892.
[8] S. Cho, H.K. Sung, S.J. Lee, W.H. Kim, D.H. Kim and Y.S. Han. 2019. Photovoltaic performance of dye sensitized solar cells containing ZnO microrods. Nanomaterials,1645.
[9] M. Tripathi and P. Chawla. Enhancement in conversion efficiency by surface modification of photoanode for natural dye sensitized solar cell. Renewable energy in the service of Mankind II (2016) 377-384.