Investigation into the Corrosion-Resistant Properties of Psidium guajava Leaf Extract on Mild Steel in Simulated Conditions

Authors

  • Aisha Siddekha

    Department of Chemistry, Government First Grade College, Tumkur 572102, India

  • Asokan Vasudevan

    Faculty of Business and Communications, INTI International University, Nilai 71800, Malaysia

    Business Administration and Management, Wekerle Business School, 1083 Budapest, Hungary

  • Lalithamba Haraluru Shankaraiah

    Department of Chemistry, Siddaganga Institute of Technology, Tumkur 572103, India

  • Yogeesh Nijalingappa

    Department of Mathematics, Government First Grade College, Tumkur 572101, India

  • Suleiman Ibrahim Mohammad

    Faculty of Business and Communications, INTI International University, Nilai 71800, Malaysia

    Department of Business Administration, Business School, Al al-Bayt University, Mafraq 25113, Jordan

DOI:

https://doi.org/10.30564/jbms.v8i3.12734
Received: 11 November 2025 | Revised: 12 December 2025 | Accepted: 3 March 2026 | Published Online: 17 July 2026

Abstract

Plant-extract inhibitors are attractive for mitigating marine and oil-and-gas corrosion while reducing toxicity and environmental persistence. Here, an aqueous Psidium guajava (guava) leaf extract was evaluated as a green inhibitor for mild steel in 5% NaCl at room temperature for 24 h, under both (i) conditions without H₂S and (ii) H₂S-souring simulated by in situ Na₂S/acetic acid. Inhibition performance was pre-screened by the weight-loss method and interpreted using adsorption-isotherm fitting and Hill-type dose-response analysis to estimate apparent adsorption/thermodynamic parameters and characteristic concentrations. To assess environmental compatibility, bioaccumulation potential (log P{o/w}), seawater biodegradation (OECD 306 BOD/COD), and a brine-shrimp toxicity screen were also assessed. The extract produced concentration-dependent inhibition with different optimum ranges depending on H₂S presence and exhibited low bioaccumulation potential and substantial biodegradation in the screening tests. Although electrochemical and surface-analytical validation is required, the combined corrosion-performance plus environmental-screening workflow suggests Psidium guajava leaf extract as a promising candidate for further development of sustainable corrosion inhibitors.

Keywords:

Psidium guajava; Mild Steel; Green Corrosion Inhibitor; Weight Loss; Adsorption Isotherm; Dose-Response; H₂S; Bioaccumulation; Biodegradation; Toxicity Screening

References

[1] Uhlig, H.H., 1963. Corrosion and Corrosion Control: An Introduction to Corrosion Science and Engineering. John Wiley & Sons: London, UK.

[2] Flores-García, B.D., Fatunla, O., Adeleye, A.O., et al., 2023. Making Sustainable Agriculture Possible Through the Utilization of Plant–Microbe Interactions. SciWaveBulletin. 1(1), 34–40. DOI: https://doi.org/10.61925/SWB.2023.1106

[3] Hossain, N., Chowdhury, M.A., Kchaou, M., 2021. An Overview of Green Corrosion Inhibitors for Sustainable and Environment Friendly Industrial Development. Journal of Adhesion Science and Technology. 35(7), 673–690. DOI: https://doi.org/10.1080/01694243.2020.1816793

[4] Rajee, A.O., 2023. Exploring the Ecological Harmony of Organic Farming Practices. SciWaveBulletin. 1(3), 29–36. DOI: https://doi.org/10.61925/SWB.2023.1304

[5] Chaubey, N., Savita, Qurashi, A., et al., 2021. Frontiers and Advances in Green and Sustainable Inhibitors for Corrosion Applications: A Critical Review. Journal of Molecular Liquids. 321, 114385. DOI: https://doi.org/10.1016/j.molliq.2020.114385

[6] Akram, N., Elyor, B., Ado, B.V., 2023. Structural Modification in Oleanolic Acid for Antiviral Activity. SciWaveBulletin. 1(2), 10–17. DOI: https://doi.org/10.61925/SWB.2023.1202

[7] Yousef, T.A., Alhamzani, A.G., Abou-Krisha, M.M., et al., 2023. Experimental and Theoretical Examinations of Triazole Linked Saccharin Derivatives as Organic Corrosion Inhibitors for Mild Steel in Hydrochloric Acid. Journal of Molecular Structure. 1275, 134603. DOI: https://doi.org/10.1016/j.molstruc.2022.134603

[8] Núñez-Rocha, G.M., Obande, J., Jain, B.N., et al., 2023. Efficient Delivery of Antiepileptic Drugs (AED’s) and Nanomedicine for the Treatment of Epilepsy. SciWaveBulletin. 1(1), 1–6. DOI: https://doi.org/10.61925/SWB.2023.1101

[9] Deyab, M.A., El-Shamy, O.A.A., Thabet, H.K., et al., 2023. Electrochemical and Theoretical Investigations of Favipiravir Drug Performance as Ecologically Benign Corrosion Inhibitor for Aluminum Alloy in Acid Solution. Scientific Reports. 13, 8680. DOI: https://doi.org/10.1038/s41598-023-35226-0

[10] Karim Azad, S.M.A., Satyanarayana, P., 2023. Tantalum Extraction and Its Wide-Ranging Significance. SciWaveBulletin. 1(4), 9–15. DOI: https://doi.org/10.61925/SWB.2023.1402

[11] Amirtharaj Mosas, K.K., Chandrasekar, A.R., Dasan, A., et al., 2022. Recent Advancements in Materials and Coatings for Biomedical Implants. Gels. 8(5), 323. DOI: https://doi.org/10.3390/gels8050323

[12] Nijalingappa, Y., Karthik, M., Vasudevan, A., et al., 2026. Assessing Eco-Efficiency of Building Materials Using Type-2 Fuzzy AHP–TOPSIS Framework. Journal of Building Material Science. 8(2), 23–40. DOI: https://doi.org/10.30564/jbms.v8i2.12600

[13] Kadhim, A., Kadhim, S.M., Elah, H.A., 2018. Enhancement of the Corrosion Resistance for 6009 Aluminum Alloy by Laser Treatment. Kufa Journal of Engineering. 9(2), 202–214. DOI: https://doi.org/10.30572/2018/kje/090215

[14] Yogeesh, N., Lingaraju, 2021. Fuzzy Logic-Based Expert System for Assessing Food Safety and Nutritional Risks. International Journal of Food and Nutritional Sciences. 10(2), 75–86.

[15] Al Jahdaly, B.A., Maghraby, Y.R., Ibrahim, A.H., et al., 2022. Role of Green Chemistry in Sustainable Corrosion Inhibition: A Review on Recent Developments. Materials Today Sustainability. 20, 100242. DOI: https://doi.org/10.1016/j.mtsust.2022.100242

[16] Yogeesh, N., 2024. Solving Fuzzy Nonlinear Optimization Problems Using Evolutionary Algorithms. In: Mukherjee, G., Basu Mallik, B., Kar, R., et al. (eds.). Advances on Mathematical Modeling and Optimization with Its Applications. CRC Press: Boca Raton, FL, USA.

[17] Ismail, N., Mujad, S.M., Zulkifli, M.F.R., et al., 2022. A Review on Application of Marine Algae as Green Corrosion Inhibitors in Acid Medium. Vietnam Journal of Chemistry. 60(4), 409–416. DOI: https://doi.org/10.1002/vjch.202200001

[18] Langmuir, I., 1918. The Adsorption of Gases on Plane Surfaces of Glass, Mica and Platinum. Journal of the American Chemical Society. 40(9), 1361–1403.

[19] Aslam, R., Mobin, M., Aslam, J., 2022. Nanomaterials as Corrosion Inhibitors. In: Verma, C., Aslam, J., Hussain, C.M. (eds.). Inorganic Anticorrosive Materials. Elsevier: Amsterdam, The Netherlands. pp. 3–20. DOI: https://doi.org/10.1016/B978-0-323-90410-0.00001-5

[20] Temkin, M.I., Pyzhev, V., 1940. Kinetics of Ammonia Synthesis on Promoted Iron Catalysts. Acta Physicochimica URSS. 12, 217–222.

[21] de Souza Morais, W.R., da Silva, J.S., Queiroz, N.M.P., et al., 2023. Green Corrosion Inhibitors Based on Plant Extracts for Metals and Alloys in Corrosive Environment: A Technological and Scientific Prospection. Applied Sciences. 13(13), 7482. DOI: https://doi.org/10.3390/app13137482

[22] Murungi, P.I., Sulaimon, A.A., 2022. Ideal Corrosion Inhibitors: A Review of Plant Extracts as Corrosion Inhibitors for Metal Surfaces. Corrosion Reviews. 40(2), 127–136. DOI: https://doi.org/10.1515/corrrev-2021-0051

[23] Mwakalesi, A.J., Nyangi, M., 2023. Effective Corrosion Inhibition of Mild Steel in an Acidic Environment Using an Aqueous Extract of Macadamia Nut Green Peel Biowaste. Engineering Proceedings. 31(1), 41. DOI: https://doi.org/10.3390/ASEC2022-13804

[24] Umoren, S.A., Abdullahi, M.T., Solomon, M.M., 2022. An Overview on the Use of Corrosion Inhibitors for the Corrosion Control of Mg and Its Alloys in Diverse Media. International Journal of Materials Research and Technology. 20, 2060–2093. DOI: https://doi.org/10.1016/j.jmrt.2022.08.021

[25] Pourzarghan, V., Fazeli-Nasab, B., 2021. The Use of Robinia pseudoacacia L. Fruit Extract as a Green Corrosion Inhibitor in the Protection of Copper-Based Objects. Heritage Science. 9, 75. DOI: https://doi.org/10.1186/s40494-021-00545-w

[26] Kwolek, P., Dychtoń, K., Kościelniak, B., et al., 2022. Gallic Acid as a Potential Green Corrosion Inhibitor for Aluminum in Acidic Solution. Metals. 12(2), 250. DOI: https://doi.org/10.3390/met12020250

[27] Phull, B., Abdullahi, A.A., 2017. Marine Corrosion. In: Hashmi, S. (ed.). Reference Module in Materials Science and Materials Engineering. Elsevier: Amsterdam, The Netherlands. pp. 1–39.

[28] Freundlich, H.M.F., 1906. Over the Adsorption in Solution. The Journal of Physical Chemistry. 57, 385–471.

[29] Wan, Z., Yang, J., 2021. Research on Corrosion Management Technology of Petroleum Pipeline and Pressure Vessel. IOP Conference Series: Earth and Environmental Science. 692, 042057. DOI: https://doi.org/10.1088/1755-1315/692/4/042057

[30] Brijder, R., Hagen, C.H.M., Cortés, A., et al., 2022. Review of Corrosion Monitoring and Prognostics in Offshore Wind Turbine Structures: Current Status and Feasible Approaches. Frontiers in Energy Research. 10, 991343. DOI: https://doi.org/10.3389/fenrg.2022.991343

[31] Abbott, W.S., 1925. A Method of Computing the Effectiveness of an Insecticide. Journal of Economic Entomology. 18(2), 265–267.

[32] Martinez Palou, R., Olivares-Xomelt, O., Likhanov, V.N., 2014. Environmentally Friendly Corrosion Inhibitors. In: Aliofkhazraei, A. (ed.). Developments in Corrosion Protection. InTechOpen: London, UK. DOI: https://doi.org/10.5772/57252

[33] Burhagohain, P., Sharma, G., 2022. Plant Extract as Green Corrosion Inhibitor for Mild Steel in Oil and Gas Industry: A Review. International Journal of Oil, Gas and Coal Technology. 31(2), 184–210. DOI: https://doi.org/10.1504/IJOGCT.2022.125381

[34] Dehghani, A., Ghahremani, P., Mostafatabar, A.H., et al., 2022. Plant Extracts: Probable Alternatives for Traditional Inhibitors for Controlling Alloys Corrosion Against Acidic Media—A Review. Biomass Conversion and Biorefinery. 14, 7467–7486. DOI: https://doi.org/10.1007/s13399-022-02893-4

[35] Naseer, S., Hussain, S., Naeem, N., et al., 2018. The Phytochemistry and Medicinal Value of Psidium guajava (Guava). Clinical Phytoscience. 4, 32. DOI: https://doi.org/10.1186/s40816-018-0093-8

[36] ASTM G1-90. 1990. Standard Practice for Preparing, Cleaning, and Evaluating Corrosion Test Specimens. American Society for Testing and Materials: West Conshohocken, PA, USA.

[37] Hagar, H.S., Forooezsh, J., Zivar, D., et al., 2020. Simulation of Hydrogen Sulfide Generation in Oil and Gas Geological Formations. In Proceedings of the 2020 International Conference on Computational Intelligence (ICCI), Bandar Seri Iskandar, Malaysia, 8–9 October 2020; pp. 121–125. DOI: https://doi.org/10.1109/ICCI51257.2020.9247695

[38] Malaret, F., 2022. Exact Calculation of Corrosion Rates by the Weight-Loss Method. Experimental Results. 3, e13. DOI: https://doi.org/10.1017/exp.2022.5

[39] Tan, B., Xiang, B., Zhang, S., et al., 2021. Papaya Leaves Extract as a Novel Eco-Friendly Corrosion Inhibitor for Cu in H2SO4 Medium. Journal of Colloid and Interface Science. 582, 918–931. DOI: https://doi.org/10.1016/j.jcis.2020.08.093

[40] Tan, B., He, J., Zhang, S., et al., 2021. Insight into anti-corrosion nature of Betel leaves water extracts as the novel and eco-friendly inhibitors. Journal of Colloid and Interface Science. 585, 287–301. DOI: https://doi.org/10.1016/j.jcis.2020.11.059

[41] Tan, B., Fu, A., Guo, L., et al., 2023. Insight into anti-corrosion mechanism of Dalbergia odorifera leaves extract as a biodegradable inhibitor for X70 steel in sulfuric acid medium. Industrial Crops and Products. 194, 116106. DOI: https://doi.org/10.1016/j.indcrop.2022.116106

[42] Tan, B., Ren, H., Liu, Y., et al., 2024. Insight into the anti-corrosion performance of crop waste as a degradable corrosion inhibitor for copper in sulfuric acid medium. Industrial Crops and Products. 222, 119654. DOI: https://doi.org/10.1016/j.indcrop.2024.119654

[43] Tan, B., Sun, X., Zhou, Z., et al., 2026. Sesame oil cake extract as corrosion inhibitor for Cu in H2SO4 medium. Applied Surface Science. 728, 166085. DOI: https://doi.org/10.1016/j.apsusc.2026.166085

[44] Zhao, W., Wan, R., Sun, X., et al., 2025. Inhibition mechanism of phosphorus-doped carbon quantum dots on anodic corrosion in neutral Mg-air batteries. Journal of Alloys and Compounds. 1037, 182609. DOI: https://doi.org/10.1016/j.jallcom.2025.182609

Downloads

How to Cite

Siddekha, A., Vasudevan, A., Shankaraiah, L. H., Nijalingappa, Y., & Mohammad, S. I. (2026). Investigation into the Corrosion-Resistant Properties of Psidium guajava Leaf Extract on Mild Steel in Simulated Conditions. Journal of Building Material Science, 8(3), 24–36. https://doi.org/10.30564/jbms.v8i3.12734