Re-examination of Hydrochemistry and Groundwater Potentials of Cross River and Imo-Kwa-Ibo Intersecting Tropical Basins of SouthSouth Nigeria

Authors

  • Saadu Umar Wali Department of Geography, Federal University Birnin kebbi, P.M.B 1157. Kebbi State, Nigeria
  • Ibrahim Mustapha Dankani Department of Geography, Usmanu Danfodiyo University Sokoto, P.M.B. 2346. Sokoto State, Nigeria.
  • Sheikh Danjuma Abubakar Department of Geography, Usmanu Danfodiyo University Sokoto, P.M.B. 2346. Sokoto State, Nigeria.
  • Murtala Abubakar Gada Department of Geography, Usmanu Danfodiyo University Sokoto, P.M.B. 2346. Sokoto State, Nigeria.
  • Kabiru Jega Umar Department of Pure and Industrial Chemistry, Federal University Birnin kebbi, P.M.B 1157. Kebbi State, Nigeria
  • Abdulqadir Abubakar Usman Department of Geography, Federal University Birnin kebbi, P.M.B 1157. Kebbi State, Nigeria
  • Ibrahim Mohammad Shera Department of Geography, Federal University Birnin kebbi, P.M.B 1157. Kebbi State, Nigeria

DOI:

https://doi.org/10.30564/jgr.v2i3.2142

Abstract

This review attempted a detailed description of geological and hydrogeological configurations of Cross River and Imo-Akwa Ibo basins. It presented a synthesis of hydrochemistry and a description of the hydrogeological configurations of the two basins. Hydrogeologically, most areas under Cross River and Imo-Kwa-Ibo are poor in terms of groundwater potentials. Based on the hydrochemistry, the basins hold water of excellent quality. Groundwater sources fall in soft to moderately hard classes. The entire sources groundwater has a TDS concentration of less than 500 mg/l. Groundwater classification based on electrical conductivity (EC) showed EC levels were less than 500 µS/cm. Most of the examined cations and anions are within WHO reference guidelines for drinking water quality. However, no broadanalysis of water quality based on water quality indices. Also, studies modeling pollution or the impact of land use changes on groundwater quality are wanting. Thus, further analysis of the hydrochemistry of groundwater aquifers is recommended.

Keywords:

Cross River Basin; Imo-Kwa-Ibo Basin; Hydrogeology; Hydrochemistry

References

[1] Carvalho Resende, T., et al. Assessment of the impacts of climate variability on total water storage across Africa: implications for groundwater resources management. Hydrogeology Journal, 2018, 27(2): 493-512.

[2] Da Silva Rangel Neto, R., L.D. Luz, T.R. Aguiar Junior. Springs’ Water Quality Assessment in Areas with Different Degrees of Forest Conservation: a Study in Tropical Climate Basins. Water, Air, & Soil Pollution, 2020, 231(227): 1-16.

[3] Dovie, D.B.K., R.A. Kasei. Hydro-climatic stress,shallow groundwater wells and coping in Ghana's White Volta basin. Sci Total Environ, 2018, 636: 1268-1278.

[4] Owusu, G., et al. Analyses of freshwater stress with a couple ground and surface water model in the Pra Basin, Ghana. Applied Water Science, 2015, 7(1): 137-153.

[5] Sharma, P.J., P.L. Patel, V. Jothiprakash. Impact of rainfall variability and anthropogenic activities on streamflow changes and water stress conditions across Tapi Basin in India. Sci Total Environ, 2019, 687: 885-897.

[6] Tenorio-Fernandez, L., A. Valle-Levinson, J. Gomez-Valdes. Subtidal hydrodynamics in a tropical lagoon: A dimensionless numbers approach. Estuarine, Coastal, and Shelf Science, 2018, 200: 49-459.

[7] Wohl, E., et al. The hydrology of the humid tropics.Nature Climate Change, 2012, 2(9): 655-662.

[8] Ayogu, C.N., et al. Hydro-geochemical analysis and quality evaluation of surface water in the Mamu River basin, southeastern Nigeria. Applied Water Science, 2020, 10(159): 1-24.

[9] Pant, R.R., et al. Spatiotemporal variations of hydro geochemistry and its controlling factors in the Gandaki River Basin, Central Himalaya Nepal. Sci Total Environ, 2018, 622-623: 770-782.

[10] Sefie, A., et al. Hydrogeochemistry and groundwater quality assessment of the multilayered aquifer in Lower Kelantan Basin, Kelantan, Malaysia. Environmental Earth Sciences, 2018, 77(10).

[11] Wagh, V.M., et al. Influence of hydro-geochemical processes on groundwater quality through geostatistical techniques in Kadava River basin, Western India. Arabian Journal of Geosciences, 2018, 12(1).

[12] Andrade, L., et al. Surface water flooding, groundwater contamination, and enteric disease in developed countries: A scoping review of connections and consequences. Environmental Pollution, 2018, 236: 540-549.

[13] Argamasilla, M., J.A. Barbera, B. Andreo. Factors controlling groundwater salinization and hydrogeo chemical processes in coastal aquifers from southern Spain. Sci Total Environ, 2017, 580: 50-68.

[14] Bao, C., et al. Understanding watershed hydrogeo chemistry: 1. Development of RT-Flux-PIHM. Water Resources Research, 2017, 53(3): 2328-2345.

[15] Coomar, P., et al. Contrasting controls on hydrogeo chemistry of arsenic-enriched groundwater in the homologous tectonic settings of Andean and Himalayan basin aquifers, Latin America and South Asia. Sci Total Environ, 2019, 689: 1370-1387.

[16] Hamutoko, J.T., et al. Hydrogeochemical and isotope study of perched aquifers in the Cuvelai-Etosha Basin, Namibia. Isotopes Environ Health Stud, 2017, 53(4): 382-399.

[17] Ordens, C.M., et al. Preface: Advances in hydrogeo logic understanding of Australia’s Great Artesian Basin. Hydrogeology Journal, 2020, 28(1): 1-11.

[18] Rajendiran, T., et al. Influence of variations in rainfall pattern on the hydrogeochemistry of coastal groundwater-an outcome of periodic observation. Environ Sci Pollut Res Int, 2019, 26(28): 29173-29190.

[19] Lamb, K.J., et al. Hydrogeophysical monitoring reveals primarily vertical movement of an applied tracer across a shallow, sloping low-permeability till interface: Implications for agricultural nitrate transport. Journal of Hydrology, 2019, 573: 616-630.

[20] Marcais, J., et al. Dating groundwater with dissolved silica and CFC concentrations in crystalline aquifers.Sci Total Environ, 2018, 636: 260-272.

[21] Shultz, C.D., et al. Simulating selenium and nitrogen fate and transport in coupled stream-aquifer systems of irrigated regions. Journal of Hydrology, 2018, 560: 512-529.

[22] Tavakoly, A.A., et al. An integrated framework to model nitrate contaminants with interactions of agriculture, groundwater, and surface water at regional scales: The STICS-EauDyssée coupled models applied over the Seine River Basin. Journal of Hydrology, 2019, 568: 943-958.

[23] Sigua, G.C., et al. Nitrogen in soils, plants, surface water, and shallow groundwater in a bahiagrass pasture of Southern Florida, USA. Nutrient Cycling in Agroecosystems, 2009, 86(2): 175-187.

[24] Van Beek, C.L., et al. Emissions of N2O from fertilized and grazed grassland on organic soil in relation to groundwater level. Nutrient Cycling in Agroeco systems, 2009, 86(3): 331-340.

[25] Wilson, A.M., J.T. Morris. The influence of tidal forcing on groundwater flow and nutrient exchange in a salt marsh-dominated estuary. Biogeochemistry, 2011, 108(1-3): 27-38.

[26] Kaliraj, S., N. Chandrasekar, N.S. Magesh. Identification of potential groundwater recharge zones in Vaigai upper basin, Tamil Nadu, using GIS-based analytical hierarchical process (AHP) technique. Arabian Journal of Geosciences, 2013, 7(4): 1385-1401.

[27] Moya, C.E., et al. Hydrochemical evolution and groundwater flow processes in the Galilee and Eromanga basins, Great Artesian Basin, Australia: a multivariate statistical approach. Sci Total Environ, 2015, 508: 411-26.

[28] Sener, E., A. Davraz. Assessment of groundwater vulnerability based on a modified DRASTIC model, GIS and an analytic hierarchy process (AHP) method: the case of Egirdir Lake basin (Isparta, Turkey). Hydrogeology Journal, 2012, 21(3): 701-714.

[29] Tweed, S., et al. Arid zone groundwater recharge and salinization processes; an example from the Lake Eyre Basin, Australia. Journal of Hydrology, 2011, 408(3-4): 257-275.

[30] Zhou, Q., et al. Modeling basin- and plume-scale processes of CO2 storage for full-scale deployment. Ground Water, 2010, 48(4): 494-514.

[31] Denchik, N., et al. In-situ geophysical and hydro-geochemical monitoring to infer landslide dynamics (Pégairolles-de-l'Escalette landslide, France). Engineering Geology, 2019, 254: 102-112.

[32] Gasperikova, E., et al. Long-term electrical resistivity monitoring of recharge-induced contaminant plume behavior. J Contam Hydrol, 2012, 142-143: 33-49.

[33] Ingebritsen, S.E., M. Manga. Hydrogeochemical precursors. Nature Geoscience, 2014, 7(10): 697-698.

[34] Neogi, B., et al. Hydrogeochemistry of coal mine water of North Karanpura coalfields, India: implication for solute acquisition processes, dissolved fluxes and water quality assessment. Environmental Earth Sciences, 2017, 76(489): 1-17.

[35] Salas, J., C. Sena, D. Arcos. Hydrogeochemical evolution of the bentonite buffer in a KBS-3 repository for radioactive waste. Reactive transport modeling of the LOT A2 experiment. Applied Clay Science, 2014. 101: p. 521-532.

[36] Singh, V.B., A.L. Ramanathan. Assessment of solute and suspended sediments acquisition processes in the Bara Shigri glacier meltwater (Western Himalaya, India). Environmental Earth Sciences, 2015, 74(3): 2009-2018.

[37] Edet, A.E., O.E. Offiong. Evaluation of water quality pollution indices for heavy metal contamination monitoring. A study case from Akpabuyo-Odukpani area, Lower Cross River Basin (southeastern Nigeria). GeoJournal, 2002, 57: 295-304.

[38] Opara, K.N., et al. Status of forest onchocerciasis in the Lower Cross River Basin, Nigeria: Entomologic profile after five years of Ivermectin intervention. The American Journal of Tropical Medicine and Hygiene, 2005, 73(3): 371-376.

[39] Akpabio, E.M. Assessing integrated water resources management in Nigeria: insights and lessons from irrigation projects in the Cross River Basin. Water Policy, 2007, 9(2): 149-168.

[40] Akpabio, E.M. Integrated water resources management in the cross river basin, Nigeria: How can we reconcile institutional boundaries and interests? International Journal of River Basin Management, 2008, 6(3): 267-276.

[41] Akpabio, E.M., et al. Integrated Water Resources Management in the Cross River Basin, Nigeria. International Journal of Water Resources Development, 2007, 23(4): 691-708.

[42] Edet, A., A. Ukpong, T. Nganje. Hydrochemical studies of Cross River Basin (southeastern Nigeria) river systems using cross plots, statistics and water quality index. Environmental Earth Sciences, 2013, 70(7): 3043-3056.

[43] Nganje, T.N., et al. Hydrochemistry of surface water and groundwater in the shale bedrock, Cross River Basin and Niger Delta Region, Nigeria. Applied Water Science, 2017. 7(2): p. 961-985.

[44] Offodile, M.E. Groundwater study and development in Nigeria. Mecon Geological and Engineering, Ltd Ehinder O, 2nd Edition, Jos, Nigeria. 2002: 453.

[45] Ekwok, S.E., et al. Assessment of groundwater potential using geophysical data: a case study in parts of Cross River State, south-eastern Nigeria. Applied Water Science, 2020, 10(144): 1-17.

[46] Sikakwe, G.U. GIS-based model of groundwater occurrence using geological and hydrogeological data in Precambrian Oban Massif southeastern Nigeria. Applied Water Science, 2018. 8(79): p. 1-13.

[47] Sikakwe, G.U., A. Otele, B.N. Ozibo. Chemical speciation and complexation modeling of trace and rare earth elements in groundwater of Oban Massif and Mamfe embayment southeastern Nigeria. Chemical Speciation & Bioavailability, 2018, 30(1): 86-98.

[48] Ugbaja, A.N., B.E. Ephraim. Physicochemical and bacteriological parameters of surface water quality in part of Oban Massif, Nigeria. Global Journal of Geological Sciences, 2019, 17(1): 13.

[49] Akpan, A.E., A.N. Ugbaja, N.J. George. Integrated geophysical, geochemical and hydrogeological investigation of shallow groundwater resources in parts of the Ikom-Mamfe Embayment and the adjoining areas in Cross River State, Nigeria. Environmental Earth Sciences, 2013. 70: p. 1435-1456.

[50] Agumanu, A.E. The Abakaliki and the Ebonyi Formations: sub-divisions of the Albian Asu River Group in the southern Benue Trough, Nigeria. Journal of African Earth Sciences, 1989, 9(1): 195-207.

[51] Amajor, L.C. Paleocurrent, petrography, and provenance analyses of the Ajali Sandstone (Upper Cretaceous), Southeastern Benue Trough, Nigeria. Sedimentary Geology, 1987, 54: 47-60.

[52] Effiong, C.I., et al. Magnetic basement depth re-evaluation of Abakaliki/Ikom and Environs Southeastern Nigeria, using 3-D Euler Deconvolution. Global Scientific Journal, 2017, 5(9): 120-138.

[53] Reijers, T.J.A., S.W. Pettersp. Depositional environments, and diagenesis of Albian carbonates on the Calabar Flank, SE Nigeria. Journal of Petroleum Geology, 1987, 10(3): 283-294.

[54] Aghamelu, O.P., P.N. Nnabo, H.N. Ezeh. Geotechnical and environmental problems related to shales in the Abakaliki area, Southeastern Nigeria. African Journal of Environmental Science and Technology, 2011, 5(2): 80-88.

[55] Okechukwu, P.A., O.O. Celestine. Geotechnical assessment of road failures in the Abakaliki Area, Southeastern Nigeria. International Journal of Civil & Environmental Engineering, 2011, 11(1): 1-21.

[56] Okogbue, C.O., O.P. Aghamelu. Comparison of the geotechnical properties of crushed shales from Southeastern Nigeria. Bulletin of Engineering Geology and the Environment, 2010, 69(4): 587-597.

[57] Cemil, B.C., et al. Does the corticotropin-releasing hormone system play a role in the pathogenesis of lichen planus? Postepy Dermatol Alergol, 2017, 34(4):322-327.

[58] Odunze-Akasiugwu, S.O., G.C. Obi. Stratigraphic relations and habitat of the Bende fish teeth, southeastern Nigeria. Arabian Journal of Geosciences, 2017, 10(11).

[59] Igwe, E.O., A.U. Okoro. Field and lithostratigraphic studies of the Eze-Aku Group in the Afikpo Synclinorium, southern Benue Trough, Nigeria. Journal of African Earth Sciences, 2016, 119: 38-51.

[60] Alani, O.A., K.W. Yaki. Structural Composition, and Significance of Sedimentary Formations in Nigeria. International Journal of Advanced Studies in Ecology, Development and Sustainability, 2016, 4(1): 1-17.

[61] Ola-Buraimo, A.O., I.M. Akaegbobi. Palynology, an important tool in evaluating sea-level changes, paleoenvironment and paleoclimatic conditions in geologic time. International Journal of Engineering Research & Technology, 2013, 2(3): 1-30.

[62] Chiadikobi, K.C., O.I. Chiaghanam. Visual Kerogen Study of the Campano-Maastrichtian Nkporo Group of Anambra Basin, Southeastern Nigeria. World News of Natural Sciences, 2018. 19: 142-154.

[63] Ayorinde, J., O. Adeigbe, S. Emmanuel. Petrography, and Biostratigraphic Studies of Campano-Maastrichtian Sequences of Anambra Basin Southeastern Nigeria. Current Journal of Applied Science and Technology, 2018, 27(2): 1-24.

[64] Bolarinwa, A.T., S.O. Idakwo, D.L. Bish. Rare-earth, and trace elements and hydrogen and oxygen isotopic compositions of Cretaceous kaolinitic sediments from the Lower Benue Trough, Nigeria: provenance and paleoclimatic significance. Acta Geochimica, 2019, 38(3): 350-363.

[65] Ikegwuonu, O.N., O.P. Umeji. Palynological age and palaeoenvironment of deposition of Mid-Cenozoic sediments around Umuahia, Niger delta basin, southeastern Nigeria. Journal of African Earth Sciences, 2016, 117: 160-170.

[66] Okeke, K.K., O.P. Umeji. Palynostratigraphy, palynofacies and palaeoenvironment of deposition of Selandian to Aquitanian sediments, southeastern Nigeria. Journal of African Earth Sciences, 2016, 120:102-124.

[67] Eze, M.O., L.I. Mamah, A.I. Oha. Integration of in situ measurement of radiometric signatures and aeroradiometric data in geologic mapping of parts of southern Benue Trough and Anambra Basin. Arabian Journal of Geosciences, 2019. 12(150): 1-12.

[68] Igwe, E.O. Composition, provenance, and tectonic setting of Eze-Aku Sandstone facies in the Afikpo Synclinorium, Southern Benue Trough, Nigeria. Environmental Earth Sciences, 2017, 76(420):1-12.

[69] Obasi, A.I., A.O.I. Selemo. Density, and reservoir properties of Cretaceous rocks in southern Benue Trough, Nigeria: implications for hydrocarbon exploration. Arabian Journal of Geosciences, 2018, 11(307): 1-14.

[70] Tijani, M.N., M.E. Nton. Hydraulic, textural and geochemical characteristics of the Ajali Formation, Anambra Basin, Nigeria: implication for groundwater quality. Environmental Geology, 2008, 56(5): 935-951.

[71] Uzoegbu, U.M. Lithostratigraphy of the Maastrichtian Nsukka Formation in the Anambra Basin, S.E Nigeria. IOSR Journal Of Environmental Science, Toxicology, and Food Technology, 2013. 5(5): p. 96-102.

[72] Edet, A. Seasonal and spatio-temporal patterns, evolution and quality of groundwater in Cross iver State, Nigeria: implications for groundwater management. Sustainable Water Resources Management, 2018, 5(2): 667-687.

[73] Odey, M.O., et al. Drinking water quality and risk implications for community health: A case study of shallow water wells and boreholes in three major communities in Northern Cross-River, Southern Nigeria. Human and Ecological Risk Assessment: An International Journal, 2017, 24(2): 427-444.

[74] Stephen, U.N., O.O. Celestine, O.O. Solomon. Analysis of hydrogeochemical facies in groundwater of upper part of Cross River Basin, southeastern Nigeria. Journal of African Earth Sciences, 2017. 131: p.145-155.

[75] Ebong, E.D., et al. Groundwater quality assessment using geoelectrical and geochemical approaches: case study of Abi area, southeastern Nigeria. Applied Water Science, 2016, 7(5): 2463-2478.

[76] Ekwe, A.C., et al. Determination of aquifer parameters from geosounding data in parts of Afikpo Sub-basin, southeastern Nigeria. Arabian Journal of Geosciences, 2020, 13(189): 1-15.

[77] Obiora, D.N., J.C. Ibuot, N.J. George. Evaluation of aquifer potential, geoelectric and hydraulic parameters in Ezza North, southeastern Nigeria, using geo electric sounding. International Journal of Environmental Science and Technology, 2015, 13(2): 435-444.

[78] Ibanga, J.I., N.J. George. Estimating geohydraulic parameters, protective strength, and corrosivity of hydrogeological units: a case study of ALSCON, Ikot Abasi, southern Nigeria. Arabian Journal of Geosciences, 2016, 9(363): 1-16.

[79] Chukwura, U.O., et al. Evaluation of hydrochemical characteristics and flow directions of groundwater quality in Udi Local Government Area Enugu State, Nigeria. Environmental Earth Sciences, 2014, 73(8): 4541-4555.

[80] Eze, M.O., I.B. Ijeh. Integration of in-situ susceptibility and petrographic data in study of the magnetic properties of some rocks of parts of Anambra Basin and Southern Benue Trough, Nigeria. The Pacific Journal of Science and Technology, 2019, 20(2): 387-395.

[81] Chukwudi, C.E., Z.U. Gabriel. Geoelectrical sounding for estimating groundwater potential in Nsukka L.G.A. Enugu State, Nigeria. International Journal of the Physical Sciences, 2010, 5(5): 415-420.

[82] Onyekuru, S.O., G.I. Nwankwor, C.Z. Akaolisa. Chemical Characteristics of Groundwater Systems in the Southern Anambra Basin, Nigeria. Journal of Applied Sciences Research, 2010, 6(12): 2164-2172.

[83] Boniface, C.E.E., O.U. Kalu. Comparative analysis of transmissivity and hydraulic conductivity values from the Ajali aquifer system of Nigeria. Journal of Hydrology, 1986, 83: 185-196.

[84] Ejeh, O.I. The Maastrichtian sedimentary successions of the Anambra basin recently exposed around Okpekpe and Imiegba: Part of the Mamu or Ajali Formation? Nigerian Journal of Science and Environment, 2016, 14(1): 38-48.

[85] Adesina, A.M., A.V. Adeola, O.A. Oladayo. Aspects of hydrocarbon potential of the Tertiary Imo Shale Formation in Anambra Basin, Southeastern Nigeria. IOSR Journal of Applied Geology and eophysics, 2017, 5(5): 74-83.

[86] Ekwenye, O.C., et al. A paleogeographic model for the sandstone members of the Imo Shale, south-eastern Nigeria. Journal of African Earth Sciences, 2014, 96: 190-211.

[87] Nfor, B.N., S.B. Olobaniyi, J.E. Ogala. Extent and Distribution of Groundwater Resources in Parts of Anambra State, Southeastern, Nigeria. Journal of Applied Sciences and Environmental Management, 2007. 11(2): p. 215 - 221.

[88] Igwe, E.O. Palynomorph Taxa Distribution in the Eze-Aku and Nkporo Shales within the Eastern Flank of Abakaliki Anticlinorium, Southeastern Nigeria. American Journal of Environmental Engineering and Science, 2017, 4(2): 8-19.

[89] Chiaghanam, O.I., et al. Sedimentology and Sequence Stratigraphy of the Eocene Nanka Formation (Ameki Group): An Evaluation of Ogbunike Reference Locality in Anambra Basin, South-Eastern Nigeria. IOSR Journal of Applied Geology and Geophysics, 2014, 2(3): 01-10.

[90] Ukpai, S.N., C.O. Okogbue, I.A. Oha. Investigation of hydrologic influence of geologic lineaments in areas of the Lower Benue Trough, Southeastern Nigeria. Journal of Earth System Science, 2019, 129(12): 1-18.

[91] Adanu, E.A. Source, and recharge of groundwater in the basement terrain in the Zaria-Kaduna area, Nigeria: applying stable isotopes. Journal of African Earth Sciences, 1991, 13(2): 229-234.

[92] Adiat, K.A.N., et al. Prediction of groundwater level in basement complex terrain using artificial neural network: a case of Ijebu-Jesa, southwestern Nigeria. Applied Water Science, 2019, 10(8): 1-14.

[93] Aizebeokhai, A.P., K.D. Oyeyemi. Geoelectrical characterization of basement aquifers: the case of Iberekodo, southwestern Nigeria. Hydrogeology Journal, 2017, 26(2): 651-664.

[94] Akinwumiju, A.S., M.O. Olorunfemi. Development of a conceptual groundwater model for a complex basement aquifer system: The case OF OSUN drainage basin in southwestern Nigeria. Journal of African Earth Sciences, 2019, 159(103574): 1-19.

[95] Ashaolu, E.D., et al. Spatial and temporal recharge estimation of the basement complex in Nigeria, West Africa. Journal of Hydrology: Regional Studies, 2020, 27(100658).

[96] Bayewu, O.O., et al. Geophysical evaluation of groundwater potential in part of southwestern basement complex terrain of Nigeria. Applied Water Science, 2017, 7(8): 4615-4632.

[97] Igwe, O., S.I. Ifediegwu, O.S. Onwuka. Determining the occurrence of potential groundwater zones using integrated hydro-geomorphic parameters, GIS, and remote sensing in Enugu State, Southeastern, Nigeria. Sustainable Water Resources Management, 2020. 6(39): p. 1-14.

[98] Nwankwoala, H.O. Localizing the strategy for achieving rural water supply and sanitation in Nigeria. African Journal of Environmental Science and Technology, 2012, 5(13).

[99] Omaka, O.N., et al. Assessment of the quality of groundwater from different parts of southeastern Nigeria for potable use. Environmental Earth Sciences, 2017, 76(344): 1-24.

[100] Udokporo, E. Assessment and Mapping of the Vulnerability of Soils in Imo State, Nigeria to Erosion Hazard Using Geographic Information System. International Journal of Environmental Monitoring and Analysis, 2015, 3(5): 245.

[101] Adamu, C.I., T.N. Nganje, A. Edet. Heavy metal contamination and health risk assessment associated with abandoned barite mines in Cross River State, southeastern Nigeria. Environmental Nanotechnology, Monitoring & Management, 2015, 3: 10-21.

[102] Ukpai, S.N., P.N. Nnabo, H.N. Eze. Groundwater facie analysis in the upper Cross River basin, southeast Nigeria. Environmental Earth Sciences, 2016, 75(1345): 1-10.

[103] Ebokaiwe, A.P., et al. Assessment of heavy metals around Abakaliki metropolis and potential bioaccu mulation and biochemical effects on the liver, kidney, and erythrocyte of rats. Human and Ecological Risk Assessment: An International Journal, 2018, 24(5): 1233-1255.

[104] Eze, C.L., L.I. Mamah, C. Israel-Cookey. Very low frequency electromagnetic (VLF-EM) response from a lead sulfide lode in the Abakaliki lead/zinc field, Nigeria. International Journal of Applied Earth Observation and Geoinformation, 2004, 5(2): 159-163.

[105] Okoro, A.U., E.O. Igwe. Lithofacies and depositional environment of the Amasiri Sandstone, southern Benue Trough, Nigeria. Journal of African Earth Sciences, 2014, 100: 179-190.

[106] Okoro, A.U., E.O. Igwe, C.S. Nwajide. Sedimentary and petrofacies analyses of the Amasiri Sandstone, southern Benue Trough, Nigeria: Implications for depositional environment and tectonic provenance. Journal of African Earth Sciences, 2016, 123: 258-271.

[107] Onwe-Moses, F.D., et al. Organic geochemical evaluation and hydrocarbon prospects of the Coniacian Awgu Formation, southern Benue Trough, Nigeria. Arabian Journal of Geosciences, 2019, 12(3).

[108] Umar, et al. Groundwater Level Fluctuation in Response to Climatic Variation and its Geotechnical Implication in Part of Awgu Shale, Central Benue Trough, Nigeria. International Journal of Advanced Geosciences, 2018, 6(2): 178-183.

[109] Edegbai, A.J., L. Schwark, F.E. Oboh-Ikuenobe, A review of the latest Cenomanian to Maastrichtian geological evolution of Nigeria and its stratigraphic and paleogeographic implications. Journal of African Earth Sciences, 2019, 150: 823-837.

[110] Umar, N.D., O. Igwe. Geo-electric method applied to groundwater protection of a granular sandstone aquifer. Applied Water Science, 2019, 9(12): 1-14.

[111] Umar, N.D., O. Igwe, I.G. Idris. Evaluation and characterization of groundwater of the Maastrichtian Lafia formation, Central Benue trough, Nigeria. Journal of Earth System Science, 2019, 128(168): 1-12.

[112] Bankole, S.A., A.O. Ola-Buraimo. Biostratigraphy, and palaeoenvironment of deposition of Nsukka Formation, Anambra Basin, southeastern Nigeria. Journal of Palaeogeography, 2017, 6(1): 45-59.

[113] Bello, R., C. Ofoha, N. Wehiuzo. Geothermal Gradient, Curie Point Depth and Heat Flow Determination of Some Parts of Lower Benue Trough and Anambra Basin, Nigeria, Using High-Resolution Aeromagnetic Data. Physical Science International Journal, 2017, 15(2): 1-11.

[114] Daniel, N.O., et al. Investigation of magnetic anomalies of Abakaliki area, Southeastern Nigeria, using high-resolution aeromagnetic data. Journal of Geology and Mining Research, 2018, 10(6): 57-71.

[115] Anakwuba, E.K., et al. Sequence stratigraphic interpretation of parts of Anambra Basin, Nigeria using geophysical well logs and biostratigraphic data. Journal of African Earth Sciences, 2018, 139: 330-340.

[116] Edegbai, A.J., L. Schwark, F.E. Oboh-Ikuenobe. Nature of dispersed organic matter and paleoxygenation of the Campano-Maastrichtian dark mudstone unit, Benin flank, western Anambra Basin: Implications for Maastrichtian Trans-Saharan seaway paleoceanographic conditions. Journal of African Earth Sciences, 2020, 162: 103654.

[117] Ocheli, A., et al. Granulometric and pebble morphometric applications to Benin Flank sediments in western Anambra Basin, Nigeria: proxies for paleoenvironmental reconstruction. Environ Monit Assess, 2018, 190(286): 1-17.

[118] Ogungbesan, G.O., T.A. Adedosu. Geochemical record for the depositional condition and petroleum potential of the Late Cretaceous Mamu Formation in the western flank of Anambra Basin, Nigeria. Green Energy & Environment, 2020, 5(1): 83-96.

[119] Edet, A., et al. Numerical Groundwater Flow Modeling of the Coastal Plain Sand Aquifer, Akwa Ibom State, SE Nigeria. Journal of Water Resource and Protection, 2014, 06(04): 193-201.

[120] Ezeh, S.C., et al. Ichnological characteristics and variability of Miocene deposits in the Cenozoic Niger Delta: Examples from cores in the Coastal Swamp and Offshore depobelts. Paleogeography, Palaeoclimatology, Palaeoecology, 2016, 454: 189-201.

[121] Asadu, A.N., W.N. Ofuyah. Miospore Biozonation and age characterization of Upper Miocene - Pliocene sediments in well X, deep offshore Niger delta. IOSR Journal of Applied Geology and Geophysics, 2017, 05(03): 06-13.

[122] Ola-Buraimo, A.O., I.M. Akaegbobi. Neogene dinoflagellate cyst assemblages of the late Miocene-Pliocene Ogwashi-Asaba sediment in umuna-1 well, Anambra basin, southeastern Nigeria. Journal of Petroleum and Gas Exploration Research, 2012, 2(6):115-124.

[123] Olayiwola, M.A., M.K. Bamford. Petroleum of the Deep: Palynological proxies for palaeoenvironment of deep offshore upper Miocene-Pliocene sediments from Niger Delta, Nigeria. Palaeontologia Africana, 2016, 50: 31-47.

[124] Amadi, A.N., P.I. Olasehinde, H.O. Nwankwoala. Hydrogeochemistry, and Statistical Analysis of Benin Formation in Eastern Niger Delta, Nigeria. International Research Journal of Pure & Applied Chemistry, 2014, 4(3): 327-338.

[125] Amadi, A.N., et al. Controlling Factors of Groundwater Chemistry in the Benin Formation of Southern Nigeria. International Journal of Engineering Science Invention, 2014, 3(3): 11-16.

[126] Major, L.C. Aquifers in the Benin Formation (Miocene Recent), Eastern Niger Delta, Nigeria: Lithostratigraphy, hydraulics, and water quality. Environmental Geology and Water Sciences, 1991, 17(2): 85-101.

[127] Irwin, A.A., E. Oghenevwede. Groundwater conditions and hydrogeochemistry of the shallow Benin Formation aquifer in the vicinity of Abraka, Nigeria. International Journal of Water Resources and Environmental Engineering, 2014, 6(1): 19-31.

[128] Inim, I.J., et al. Hydrogeochemical evaluation of groundwater in coastal alluvial aquifer of Akwa Ibom, Southeastern Nigeria. Journal of Coastal Sciences, 2017, 4(2): 1-8.

[129] George, N.J., J.I. Ibanga, A.I. Ubom. Geoelectro hydrogeological indices of evidence of ingress of saline water into fresh water in parts of coastal aquifers of Ikot Abasi, southern Nigeria. Journal of African Earth Sciences, 2015, 109: 37-46.

[130] George, N.J., et al. Estimating the indices of inter-transmissibility magnitude of active surficial hydrogeologic units in Itu, Akwa Ibom State, southern Nigeria. Arabian Journal of Geosciences, 2018, 11(134): 1-16.

[131] George, N.J., A.E. Akpan, B. Obot. Resistivity Study of Shallow Aquifers in the Parts of Southern Ukanafun Local Government Area, Akwa Ibom State, Nigeria. E-Journal of Chemistry, 2010, 7(3): 693-700.

[132] Uwa, U.E., G.T. Akpabio, N.J. George. Geohydro dynamic Parameters and Their Implications on the Coastal Conservation: A Case Study of Abak Local Government Area (LGA), Akwa Ibom State, Southern Nigeria. Natural Resources Research, 2018, 28(2): 349-367.

[133] Ajayi, O., O. Umoh. Quality of groundwater in the Coastal Plain Sands Aquifer of the Akwa Ibom State, Nigeria. JournalofAfrican Earth Sciences, 1998. 27(2): 259-275.

[134] Edet, A. An aquifer vulnerability assessment of the Benin Formation aquifer, Calabar, southeastern Nigeria, using DRASTIC and GIS approach. Environmental Earth Sciences, 2013, 71(4): 1747-1765.

[135] Ibe Sr, K., A. Sowa. Hydrology of part of the Oramiriukwa River basin, southeast of Owerri, Imo State, Nigeria. Hydrogeology Journal, 2002, 10(4): 509-521.

[136] Igboekwe, M.U., V.V.S. Gurunadha Rao, E.E. Okwueze. Groundwater flow modeling of Kwa Ibo River watershed, southeastern Nigeria. Hydrological Processes, 2008, 22(10): 1523-1531.

[137] Aisuebeogun, A.O., I.C. Ezekwe. Channel dynamics and hydraulic geometry of two tropical deltaic catchments in Southern Nigeria. Landform Analysis, 2014, 27: 3-13.

[138] Amajor, L.C. Aquifers in the Benin Formation (Miocene Recent), Eastern Niger Delta, Nigeria: Lithostratigraphy, Hydraulics, and Water Quality. Environmental Geology and Water Sciences, 1991, 17(7): 85-101.

[139] Ibeneme, S.I., et al. Vertical electrical sounding for aquifer characterization around the Lower Orashi River Sub-Basin Southeastern Nigeria. Communications in Applied Sciences, 2014, 2(1): 36-51.

[140] Enetimi, I.S., C.N.A. Tariwari, C.O. Blessing. Phys icochemical quality assessment of River Orashi in Eastern Niger Delta of Nigeria. Journal of Environmental Treatment Techniques, 2016, 4(4):143-148.

[141] Amangabara, G. Drainage Morphology of Imo Basin in the Anambra - Imo River Basin Area, of Imo State, Southern Nigeria. Journal of Geography, Environment and Earth Science International, 2015, 3(1): 1-11.

[142] Essien, J.P., S.P. Antai, A.A. Olajire. Distribution, Seasonal Variations and Ecotoxicological Significance of Heavy Metals in Sediments of Cross River Estuary Mangrove Swamp. Water, Air, and Soil Pollution, 2009, 197(1-4): 91-105.

[143] WHO. Guidelines for drinking-water quality: Fourth edition incorporating the first addendum. WHO Library Cataloguing-in-Publication Data. World Health Organization Geneva. 2018: 631.

[144] Zoeteman, B.C.J., G.J. Piet, L. Postma. Taste as an indicator quality. Research and Technology Journal AWWA, 1980: 537-540.

[145] De França Doria, M. Factors influencing public perception of drinking water quality. Water Policy, 2010, 12(1): 1-19.

[146] Olumuyiwa, I.O. Groundwater: Characteristics, qualities, pollutions and treatments: An overview. International Journal of Water Resources and Environmental Engineering, 2012, 4(6): 162-170

[147] Edima-Nyah, A.P., S.P. Ukwo. Physicochemical, bacteriological and risk-to-health analysis of drinking water quality in some oil-producing areas of Akwa Ibom State, Nigeria. Internet Journal of Food Safety, 2013. 15: p. 109-114.

[148] Essien, O.E., E.D. Bassey. Spatial Variation of Borehole Water Quality with Depth in Uyo Municipality, Nigeria. International Journal of Environmental Science, Management, and Engineering Research, 2012. 1(1): 1-9.

[149] Barnes, I., et al. Geochemistry of highly basic calcium hydroxide groundwater in Jordan. Chemical Geology, 1982, 35: 147-154.

[150] Gu, B., et al. Geochemical reactions and dynamics during titration of a contaminated groundwater with high uranium, aluminum, and calcium. Geochimica et Cosmochimica Acta, 2003, 67(15): 749-2761.

[151] Schot, P.P., M.J. Wassen. Calcium concentrations in wetland groundwater in relation to water sources and soil conditions in the recharge area. Journal of hydrology, 1993, 141: 197-217.

[152] EPA, Parameters of water quality: Interpretation and Standards. An Ghniomhaireacht um Chaomhnu Comhshaoil. Ireland. 2001, 132.

[153] Wali, S.U., et al. Evaluation of shallow groundwater in cretaceous and tertiary aquifers of northern Kebbi State, Nigeria. SF Journal of Environmental and Earth Sciences, 2018, 1(1): 1-11.

[154] Chapman, P.J., B. Reynolds, H.S. Wheater, Sources and controls of calcium and magnesium in storm runoff: the role of groundwater and ion exchange reactions along water flowpaths. Hydrology and Earth System Sciences, 1997, 1(3): 671-685.

[155] Magaritz, M. and U. Kafri, Concentration of magnesium in carbonate nodules of soils: an indication of fresh groundwater contamination by intruding seawater. Chemical Geology, 1979, 27:143-155.

[156] Rapant, S., et al. Impact of Calcium and Magnesium in Groundwater and Drinking Water on the Health of Inhabitants of the Slovak Republic. International Journal of Environmental Research and Public Health, 2017, 14(278): 1-22.

[157] Ukpong, E., et al. Assessment of water quality from boreholes in Ikot Akpaden and some surrounding villages of Mkpat Enin Local Government Area of Akwa Ibom State, Nigeria. Chemistry and Materials Research, 2017, 9(2): 24-29.

[158] Essien, O.E., A.E. Abasifreke. Spatial distribution and variability of groundwater quality in state capital and contiguous local government areas under urbanization expansion. American Journal of Water Resources, 2014. 2(2): 1-9.

[159] WHO. Guidelines for Drinking-water Quality. Third Edition Incorporating The First And Second Addenda: Recommendations. World Health Organization Geneva, 2008, 1: 668.

[160] Afiukwa, J., A. Eboatu. Analysis of spring water quality in Ebonyi South Zone and its health impact. American Journal of Scientific and Industrial Research, 2013, 4(2): 231-237.

[161] Adedeji, A., A. Babatunde, A. Aderemi. Hydrochemical investigation of Groundwater quality in selected locations in Uyo, Akwa-Ibom state of Nigeria. New York Science Journal, 2010: 117-122.

[162] WHO. Guidelines for Drinking-water Quality: Fourth Edition. World Health Organization Geneva, 2011: 564.

[163] McAleer, E.B., et al. Groundwater nitrate reduction versus dissolved gas production: A tale of two catchments. Sci Total Environ, 2017, 586: 372-389.

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Wali, S. U., Dankani, I. M., Abubakar, S. D., Gada, M. A., Umar, K. J., Usman, A. A., & Shera, I. M. (2020). Re-examination of Hydrochemistry and Groundwater Potentials of Cross River and Imo-Kwa-Ibo Intersecting Tropical Basins of SouthSouth Nigeria. Journal of Geological Research, 2(3), 25–42. https://doi.org/10.30564/jgr.v2i3.2142

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Vol. 2 , Iss. 3 (July 2020)

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Copyright © 2020 Saadu Umar Wali, Ibrahim Mustapha Dankani, Sheikh Danjuma Abubakar, Murtala Abubakar Gada, Kabiru Jega Umar, Abdulqadir Abubakar Usman, Ibrahim Mohammad Shera

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