Investigation of Miocene Methane Hydrate Generation Potential in the Transylvanian Basin, Romania

Authors

  • Unger, Z. ELTE University, Szombathely, Hungary; Oil & Gas Development Central Kft., Budapest, Hungary
  • LeClair, D. Oil & Gas Development Central Kft., Budapest, Hungary
  • Györfi, I. RomGaz, Târgu Mureș, Romania

DOI:

https://doi.org/10.30564/agger.v4i2.4413

Abstract

In geology we often revise theoretical models; upon finding new evidence,such as the discovery of methane hydrates, the initial model will be challenged immediately. Hereby the authors put forward two postulates:1) There is a third, previously unexplored source of methane in the Transylvanian Basin, based on a new theoretical approach on methane hydrate formation; 2) The dissociation of methane hydrates creates a strong chlorinity anomaly. Based on a recent analogy with the Black Sea basin model, we apply our statements to the Transylvanian Basin. Using direct and indirect indicators and the published system tract analysis, we claim that there are substantial grounds to believe that this model of methane hydrate formation applies to the Miocene Transylvanian Basin. Due to the increase of the geothermal gradient as a result of the volcanic activity from the Eastern Carpathians, the clathrates dissociated into methane and freshwater. This process of dilution resulted in a chlorinity anomaly that can be spotted in the formation waters of several gas fields from the Transylvanian Basin.

Keywords:

Deep hypersaline anoxic basin, Methane hydrates, Methane hydrate dissociation, Chlorinity anomaly

References

[1] Papp, K., 1911. Potassium salt exploration in Hungary, Geological Bulletin of the Hungarian Geological Society, Budapest. XLI/41, 1-19. (in Hungarian)

[2] Krézsek, Cs., Filipescu, S., 2005. Middle to late Miocene sequence stratigraphy of the Transylvanian Basin (Romania). Tectonophysics. 410, 437-463.DOI: https://doi.org/10.1016/j.tecto.2005.02.018

[3] Krézsek, Cs., Bally, W.A., 2006. The Transylvanian Basin (Romania) and its relation to the Carpathian fol and thust belt: Insights in gravitational salt tectonics,Marine and Petroleum Geology. 23,405-442.DOI: https://doi.org/10.1016/j.marpetgeo.2006.03.003

[4] Krézsek, Cs., Filipescu, S., Silye, L., et al., 2010. Miocene facies associations and sedimentary evolution of the Southern Transylvanian Basin (Romania):Implications for hydrocarbon exploration, Marine and Petroleum Geology. 27, 191-214.DOI: https://doi.org/10.1016/j.marpetgeo.2009.07.009

[5] Mațenco, L., Krézsek, Cs., Merten, S., et al., 2010.Characteristics of collisional orogens with low topographic build-up: an example from the Carpathians,Terra Nova. 22, 155-165. DOI: https://doi.org/10.1111/j.1365-3121.2010.00931.x

[6] Unger, Z., LeClair, D., 2018. Salt and Methane Generation Initiated by Membrane Polarisation. Earth Sciences. 7(2), 53-57.DOI: https://doi:10.11648/j.earth.20180702.12

[7] Tiliță, M., Lenkey, L., Mațenco, L., et al., 2006.Neogene evolution of Transylvania basin: insights derived from (2D steady-state) thermal modelling.Geophysical Research Abstracts. 8, 08874. SRef-ID:1607-7962/gra/EGU06-A-08874.

[8] Tămaş, D.T., Schléder, Zs., Krézsek, Cs., et al., 2018.Understanding salt in orogenic settings: The evolution of ideas in the Romanian Carpathians, AAPG Bulletin. 102(6), 941-958.DOI: https://doi.org/10.1306/0913171615517088

[9] Böckh, J., 1911. Notes about the anticlines with gas reserves from the Transylvanian Basin,Geological Bulletin of the Hungarian Geological Society, Budapest. XLI, 235-239. (in Hungarian)

[10] Paraschiv, D., 1979. Romanian Oil and Gas Fields,Studii Tehnice și Economice/Geological and Geophysical Institute/Technical and Economic Studies.Seria A, Bucharest. 13, 382.

[11] Nemeșan, M., 2007. Romgaz. Present and Perspectives. Energy in Centre and Eastern Europe Forum,Bucharest.

[12] Zander, T., Haeckel, M., Berndt, C., et al., 2017. On the origin of multiple BSRs in the Danube deep-sea fan, Black Sea: Earth and Planetary Science Letters.462, 15-25.DOI: https://doi.org/10.1016/j.epsl.2017.01.006

[13] Minshull, T.A., Marín-Moreno, H., Betlem, P., et al.,2019. Hydrate occurrence in Europe: A review of available evidence, Marine and Petroleum Geology.DOI: https://doi.org/10.1016/j.marpetgeo.2019.08.014.

[14] Reeburgh, W.S., Ward, B.B., Whalen, St.C., et al.,1991. Black Sea methane geochemistry, Deep Sea Research Part A. Oceanographic Research Papers.38(2), S1189-1210, ISSN 0198-0149.DOI: https://doi.org/10.1016/S0198-0149(10)80030-5

[15] Crânganu, C., Deming, D., 1996. Heat flow and hydrocarbon generation in the Transylvanian Basin,Romania. AAPG Bulletin. 10, 1641-1653.DOI: https://doi.org/10.1306/64EDA0E6-1724-11D7-8645000102C1865D

[16] Haeckel, M., Zander, T., Burwicz, E., et al., 2017.The gas hydrate system of the Danube deep-sea fan in the Black Sea, In Proceedings of the 9th Internaional Conference on Gas Hydrates, Denver,1680 Colorado, USA.

[17] Unger, Z., LeClair, D., 2016. Is the Badenian Salt Deposit in Transylvania a Secondary Source of Methane? In Proceedings of the AAPG European Regional Conference and Exhibition, Bucharest, Romania. May 19-20, 112.

[18] Krézsek, Cs., 2011. Petroleum systems of Romania,AAPG Search and Discovery Article #10349.

[19] Paraschiv, D., 1979. Romanian Oil and Gas Fields.Institutul de Geologie și Geofizică, Studii Tehnice și Economice Seria A, Bucharest. 13, 382.

[20] Popescu, B.M., 1995. Romania’s petroleum systems and their remaining potential, Petroleum Geoscience.1, 337-350.

[21] Yakimov, M.M., La Cono, V., Slepak, V.Z., et al.,2013. Microbial life in the Lake Medee, the largest deep-sea salt-saturated formation. Scientific Reports.3, 3554.DOI: https://doi.org/10.1038/srep03554

[22] Etiope, G., Schwietzke, S., 2019. Global geological methane emissions: An update of top-down and bottom-up estimates, Elementa: Science of the Anthropocene. 7, 47.DOI: https://doi.org/10.1525/elementa.383

[23] Unger, Z., LeClair, D., 2017. Parallel Salt and Methane Generation, Possible Paradigm Shifts for Salt Generation in Deep Sea Processes, AAPG Search and Discovery Article #51392.

[24] MedRIFF Consortium, 1995, Three brine lakes discovered in the seafloor of the Eastern Mediterranean.EOS, Transactions of American Geophysical Union.76, 313.

[25] Karisiddaiah, S.M., 2000. Diverse methane concentrations in anoxic brines and underlying sediments,eastern Mediterranean Sea Deep-Sea Research I. 47,1999-2008.DOI: https://doi.org/10.1016/S0967-0637(00)00010-8

[26] Radu, Gh., Sandu, V., 2015. Evolution of the cryohydrate in the Black Sea. Prognostic reserves and possible produceing technologies. Monitorul de Petrol si Gaze. XIV, nr.2(156), 2-5. (in Romanian)

[27] Vassilev, A., Dimitrov, L., 2002. Spatial and quantity evaluation of the Black Sea gas hydrates.Russian Geology and Geophysics. 43, 672-684. UDC 550.42:552.578.1(262.5).

[28] Seghedi, A., Rădan, S., Briceag, A., 2020. The geological heritage of the transylvanian basin: assessment of geological reserves with mud volcanoes,Geo-Eco-Marina. 26, 169-186.DOI: https://doi.org/10.5281/zenodo.4692876

[29] Unger, Z., Timár, G., 2005. Lineament map of Székelyföld based on a Landsat-TM satellite image, Hungarian Geological Bulletin. 135/2, 293-304. ISSN 0015-542X. (in Hungarian)

[30] Gál, A., Unger, Z., 2008. Relationship between mud volcanoes and lineaments, 33rd International Geological Congress, Oslo, Norwegia, 6-14. August, Pro-ceeding booklet (CD). pp. 218.

[31] Spulber, L., Etiope, G., Baciu, C., et al., 2010. Methane emission from natural gas seeps and mud volcanoes in Transylvania (Romania), Geofluids. 10, 463-475.DOI: https://doi.org/10.1111/j.1468-8123.2010.00301.x

[32] Long, D., Jackson, P.D., Lovell, M.A., et al., 2005.Methane hydrates: problems in unlocking their potential, In Dore, A.G.& Vining, B.A. (eds) Petroleum Geology: North-West Europe and Global Perspectives - Proceedings of the 6th Petroleum Geology Conference Ltd. Published by the Geological Society,London. pp. 723-730.DOI: https://doi.org/10.1144/0060723

[33] Unger, Z., LeClair, D., Györfi, I., 2020. Methane Hydrates as a Tertiary Methane Source in the Transylvanian Basin* AAPG Search and Discovery Article #11307

Downloads

How to Cite

Z., U., D., L., & I., G. (2022). Investigation of Miocene Methane Hydrate Generation Potential in the Transylvanian Basin, Romania. Advances in Geological and Geotechnical Engineering Research, 4(2), 1–8. https://doi.org/10.30564/agger.v4i2.4413

Issue

Article Type

Article