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Geochemical Characterization of Mineralized Pegmatites around Wowyen Areas, Akwanga, Northcentral Nigeria
DOI:
https://doi.org/10.30564/agger.v4i1.4314Abstract
This study aims to account for the petrogenesis and mineralization of pegmatites around the Wowyen area, northcentral basement complex,Nigeria. Field studies, petrography and whole rock geochemistry (Major oxides were estimated by X-Ray Fluorescence while the trace elements were estimated by Inductively Coupled Plasma Mass Spectrometry) where the methods adopted. The pegmatites around Wowyen area are emplaced in the remobilized belt of the Nigerian Basement complex. They are predominantly complex pegmatites (rare-metal pegmatites) which are intruded in the biotite-muscovite gneiss while the simple pegmatites intruded more in the migmatitic banded gneiss. The major components of the complex pegmatites are quartz, albite and muscovite and tourmaline.The accessory constituents are garnet; ilmenites; cassiterite-columbitetantalite oxides in contrast to quartz, microcline and biotite of the simple pegmatites. The complex pegmatites show higher peraluminous than the simple pegmatites, however, higher fractionation is observed in the complex pegmatites than the simple pegmatites. The complex pegmatites are rather enriched in rare elements such as Li, Rb, B, Cs, Sn, Nb, Be and Ta and show low ratios in Al/Ga and K/Rb than the simple pegmatites. The pegmatites are likely product of sedimentary origin and originated from post-collisional tectonic event.
Keywords:
Rare-metal pegamatites; Geochemistry; Basement complex; Pan-African events; WowyenReferences
[1] Selway, J.B., Breaks, F.W., Tindle, A.G., 2005. A review of rare-element (Li-Cs-Ta) pegmatite exploration techniques for the Superior Province, Canada,and large worldwide tantalum deposits.Explor. Min.Geol. 14(1-4), 1-30.
[2] Linnen, R.L., Lichtervelde, V.M., Černy, P., 2012.Granitic Pegmatites as Sources of Strategic Metals.Elements: An International Magazine of Mineralogy,Geochemistry, and Petrology. 8(4),275-280.
[3] Cerny, P. 1991a. Fertile granites of Precambrian rare-element pegmatite fields: Is geochemistry controlled by tectonic setting or source lithologies? Precambrian Research. 51, 429-468.
[4] Cerny, P., Ercit, T.S., 2005. The Classification of granitic pegmatites revisited. Can. Mineral. 43, 2005-2026.
[5] Ginsburg, A.I., Timofeyev, I.N., Feldman, L.G.,1979. Principles of geology of the granitic pegmatites: Nedra Moscow. pp. 296. [in Russian]
[6] Grant, N.K., 1970. Geochronology of Precambrian basement rocks from Ibadan, southwestern Nigeria.Earth Planet. Sci. Lett. 10, 29-38.
[7] Matheis, G., Caen-Vachette, M., 1983. Rb-Sr isotopic study of rare-metal bearing and barren pegmatites in the Pan-African reactivation zone of Nigeria. J. Afr.Earth Sci. 1, 35-40.
[8] Obiora, S.C., Ukaegbu, V.U., 2008. Petrology and geochemical characteristics of Precambrian granitic basement complex rocks in the southernmost part of North-Central Nigeria. Chinese J.Geochem. 28, 377-385.
[9] Jacobson, R., Webb, J.S., 1946. The pegmatites of Central Nigeria. Geological Surveying of Nigeria Bulletin. 17, 61.
[10] Wright, J.B., 1970. Controls of mineralization in the Older and Younger Tin Fields of Nigeria.Econ. Geol.65, 945-951.
[11] Matheis, G., 1987. Nigerian rare-metal pegmatites and their lithological framework. In: African Geology Reviews. Bowden, P., Kinnaird, J.A., (Eds.). Geol. J.22, 271-291.
[12] Kuster, D., 1990. Rare-metal pegmatites of Wamba,central Nigeria - their formation in relationship to late Pan - African granites. Miner. Deposita. 25, 25-33.
[13] Chukwu, A., Obiora, S.C., 2021a. Petrogenetic characterization of pegmatites and their host rocks in southern Akwanga, North-Central Basement Complex, Nigeria. Journal of Earth System Science.130(18), 1-23.DOI: https://doi.org/10.1007/s12040-020-01498-7.
[14] Chukwu, A., Obiora, S.C., 2021b. Petrology and geochemistry of pegmatites and associated rocks in Wamba areas, northcentral basement complex, Nigeria: implications for petrogenesis and rare-metal mineralizations. Arabian Journal of Geosciences.14(906), 1-20.DOI: https://doi.org/10.1007/s12517-021-07284-z
[15] Chukwu, A., Obiora, S.C., 2021c. Geochemistry of LCT pegmatites in part of Northeastern areas of Nasarawa State, Northcentral Nigeria. Explore newsletter. 192, 1-15.
[16] Garba, I., 2003. Geochemical discrimination of newly discovered rare-metal bearing and barren pegmatites in the Pan-African (600 ± 150) basement of northern Nigeria. Applied Earth Sci.(Transactions of the Institution of Mining and Metalurgy, Section B).112, 287-292.
[17] Okunlola, O.A., King, P., 2003. Process test work for the recovery of Ta 205 concentrates from rare meal bearing pegmatites of Nasarawa area, central Nigeria. Global J. Geol. 1(1), 10-15.
[18] Ekwueme, B.N., Matheis, G., 1995. Geochemistry and economic value of pegmatites in the Precambrian basement of southeast Nigeria. In: Magmatism in relation to diverse tectonic settings (Eds. R. K. Srivastava and R. Chandra), New Delhi, Oxford & IBH Publishing Co. 375-392.
[19] Adekeye, J.I.D., Akintola, O.F., 2007. Geochemical features of rare metal pegmatites in Nassarawa area, central Nigeria. J. Min. Geol. 43(1), 15-21.
[20] Akintola, O.F., Adekeye, J.I.D., 2008. Mineralization potentials of Pegmatites in the Nasarawa area of central Nigeria. Earth Sci. Res. J. 12(2), 213-234.
[21] Akoh, J.U., Ogunleye, P.O., Aliyu, A.I., 2015. Geochemical evolution of micas and Sn-, Nb-, Ta- mineralization associated with the rare metal pegmatite in Angwan Doka, central Nigeria. J. Afr. Earth Sci. 97,167-174.
[22] Crouse, R.A., Cerny, P., 1972. The Tanco pegmatite at Birnic Lake, Manitoba; I, Geology and paragenesis. Can. Mineral. 11, 591-608.
[23] Stilling, A., Cerny, P., Vanstone, P.J., 2006. The Tanco Pegmatite at Bernic Lake, Manitoba, XVI, Zonal and bulk compositions and their petrogenetic significance, Can. Mineral. 44, 599-623.
[24] Goodenough, K.M., Lusty, P.A.J., Roberts, N.M.W.,Key, R.M., Garba, A., 2014. Post- collisional Pan-African granitoids and rare metal pegmatites in western Nigeria: Age, petrogenesis, and the ‘pegmatite conundrum’. Lithos. 200-201, 22-34.
[25] Burke, K.C., Dewey, J.F., 1972. Orogeny in Africa.In: Dessauvagie T F J, Whiteman A J (eds) Africa geology. University of Ibadan Press, Ibadan. pp 583-608.
[26] Black, R., Caby, R., Moussine-Pouchkine, A., Bertrand, J.M., Fabre, J., Lesquer, A., 1979.Evidence for the Late Precambrian plate tectonics in West Africa.Nature. 278, 223-227.
[27] McCurry, P., Wright, J.B., 1977. On place and time in orogenic granite plutonism. J. Geol. Soc. Am. 82(6),1713-1716.
[28] Obiora, S.C., 2005. Field Descriptions of Hard Rocks with examples from the Nigerian Basement Complex (1st Edition). Snap Press (Nig.) Ltd. Enugu.
[29] Jones, H.A., Hockey, R.D., 1964. The geology of part of southwestern Nigeria. Nigeria Geological Surveying Bulletin. 31, 87.
[30] Dada, S.S., Respaut, J.P., 1989. The quartz fayalite monzonite (bauchite) of Bauchi, new evidence of a syntectonic Pan-African magmatism in northern Nigeria. Comptes Rendus Academie Science de Paris.309, 887-892.
[31] De la Roche, H., Leterrier, J., Grandclaude, P., Marchal, M., 1980. A classification of volcanic and plutonic rocks using R1-R2 diagrams and major-element analyses: Its relation with current nomenclature.Chem. Geol. 29, 183-210.
[32] Wedepohl, K.H., 1995. The composition of the continental crust. Geochim Cosmochim Acta. 59, 1217-1232.
[33] Cerny, P., Meintzer, R.E., 1988. Fertile granites in the Archean and Proterozoic fields of rare element pegmatites: Crustal environment, geochemistry and petrogenetic relationships. In Recent Advances in the Geology of Granite-related Mineral Deposits. Can.Institute of Mining and Metallurgy, Spec. Publ. 39,170-206.
[34] Maniar, P.D., Piccoli, P.M., 1989. Tectonic discrimination of granitoids. Geol. Soc. Am. Bull. 101, 635-643.
[35] Peccerillo, A., Taylor, S.R., 1976. Geochemistry of Eocene calc-alkaline volcanic rocks from the Kastamonu area, Northern Turkey. Contrib. Mineral.Petrol. 73, 69-87.
[36] Frost, B.R., Barnes, C.G., Collins, W.J., Arculus, R.J.,Ellis, D.J., Frost, C.D., 2001. A geochemical classification for granitic rocks. Petrol. 42, 2033-2048.
[37] Okunlola, O.A., Oyedokun, M.O., 2009. Compositional trends and rare metal Ta-Nb mineralization potential of pegmatite and associated lithologies of Igbeti Area, South-western Nigeria. RMZ-Materials and Geoenvironment. 56(1), 38-53.
[38] Ibe, C.U., Obiora, S.C., 2019. Geochemical characterization of granitoids in Katchuan Irruan area:further evidence for peraluminous and shoshonitic compositions and post-collisional setting of granitic rocks in the Precambrian Basement Complex of Nigeria. Acta Geochim.DOI: https://doi.org/10.1007/s11631-019-00318-0
[39] Christiansen, E.H., Stuckless, J.S., Funkhouser-Marolf, M.J., Howell, K.H., 1993. Petrogenesis of rare metal granites from depleted sources: an example from the Cenozoic of western Utah. Recent Advances in the Geology of granite-related mineral deposits.pp. 307-321.
[40] Ablelfadil, K.M., Asimow, P.D., Azer, M.K., Gahlan,H.A., 2016. Genesis and petrology of Late Neoproterozoic pegmatites and aplites associated with the Taba metamorphic complex in southern Sinai, Egypt.Geochem. Acta. 14(3), 219-233.
[41] Chukwu, A., Obiora, S.C., 2014. Whole-rock geochemistry of basic and intermediate intrusive rocks in the Ishiagu area: further evidence of anorogenic setting of the Lower Benue rift, southeastern Nigeria.Turk. J. Earth Sci. 23, 427-443.
[42] McDonough, W.F., Sun, S.S., 1995. The composition of the Earth. Chem. Geol. 120, 223-253.
[43] Pearce, J.A., Harris, N.B.W., Tindle, A.G., 1984.Trace element discrimination diagrams for the tectonic interpretation of granitic rocks. Petrol. 25, 956-983.
[44] Cerny, P., London, D., Novak, M., 2012. Granitic pegmatites as reflections of their sources. Elements.8, 257-261.
[45] Cerny, P., Burt, D.M., 1984. Paragenesis, crystallochemical character· istics and geochemical evolution of micas in granitic pcgmatites. In: Micas.Bailey, S.W., (Ed.}, Reviews in Mineralogy. 13, 257-297.
[46] Zhu, Y.F., Zeng, Y., Gu, L., 2006. Geochemistry of the rare metal-bearing pegmatite no. 3 vein and related granites in the Keketuohai region, Altay Mountains, northwest China. Asian Earth Sc. 27, 61-77.
[47] Shaw, R.A., Goodenough, K.M., Roberts, N.M.W.,Horstwood, M.S.A., Chenery, S.R., Gunn, A.G.,2016. Petrogenesis of rare-metal pegmatites in highgrade metamorphic terranes: A case study from the Lewisian Gneiss Complex of north-west Scotland.Precambrian Res. 281 338-362.
[48] Taylor, S.R., McLennan, S.M., 1985. The continental crust; its composition and evolution; an examination of the geochemical record preserved in sedimentary rocks Blackwell.
[49] Cerny, P., 1989. Contrasting geochemistry of two rocks, Blackwell.pegmatite fields in Manitoba: products of juvenile Aphebian crust and polycyclic Archean evolution.Precambrian Res. 45, 215-234.
[50] Akintola, A.I., Ikhane, P.R., Okunlola, O.A., Akintola, G.O., Oyebolu, O.O., 2012. Compositional features of Precambrian pegmatites of Ago-Iwoye area,southwestern, Nigeria. J. ecol. Nat. Environ 4(3),71-87.
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